What starting materials are needed to synthesize each compound by a thermal [ 4 + 2 ] cycloaddition? a. b. c.

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Answer 1

Textbook Question

Chapter 27, Problem 27.41P

What starting materials are needed to synthesize each compound by a thermal [ 4 + 2 ] cycloaddition?

a. Chapter 27, Problem 27.41P, 27.41 What starting materials are needed to synthesize each compound by a thermal , example 1 b. c.

Expert Solution

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 1

Figure 1

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 2

Figure 2

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. Therefore, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 3

Figure 3

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 4

Figure 4

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on same sides. Therefore, both the substituents are present on the same side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 5

Figure 5

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 6

Figure 6

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on opposite sides. Therefore, both the substituents are present on the opposite side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

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Answer 2

Textbook Question

Chapter 27, Problem 27.41P

What starting materials are needed to synthesize each compound by a thermal [ 4 + 2 ] cycloaddition?

a. Chapter 27, Problem 27.41P, 27.41 What starting materials are needed to synthesize each compound by a thermal , example 1 b. c.

Expert Solution

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 1

Figure 1

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 2

Figure 2

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. Therefore, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 3

Figure 3

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 4

Figure 4

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on same sides. Therefore, both the substituents are present on the same side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 5

Figure 5

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 6

Figure 6

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on opposite sides. Therefore, both the substituents are present on the opposite side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

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Answer 3

Textbook Question

Chapter 27, Problem 27.41P

What starting materials are needed to synthesize each compound by a thermal [ 4 + 2 ] cycloaddition?

a. Chapter 27, Problem 27.41P, 27.41 What starting materials are needed to synthesize each compound by a thermal , example 1 b. c.

Expert Solution

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 1

Figure 1

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 2

Figure 2

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. Therefore, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 3

Figure 3

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 4

Figure 4

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on same sides. Therefore, both the substituents are present on the same side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 5

Figure 5

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 6

Figure 6

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on opposite sides. Therefore, both the substituents are present on the opposite side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Textbook Question

Chapter 27, Problem 27.41P

What starting materials are needed to synthesize each compound by a thermal [ 4 + 2 ] cycloaddition?

a. Chapter 27, Problem 27.41P, 27.41 What starting materials are needed to synthesize each compound by a thermal , example 1 b. c.

Expert Solution

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 1

Figure 1

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 2

Figure 2

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. Therefore, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 3

Figure 3

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 4

Figure 4

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on same sides. Therefore, both the substituents are present on the same side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 5

Figure 5

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 6

Figure 6

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on opposite sides. Therefore, both the substituents are present on the opposite side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

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Answer 5

Textbook Question

Answer 6

Textbook Question

Answer 7

Expert Solution

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 1

Figure 1

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 2

Figure 2

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. Therefore, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 3

Figure 3

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 4

Figure 4

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on same sides. Therefore, both the substituents are present on the same side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 5

Figure 5

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 6

Figure 6

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on opposite sides. Therefore, both the substituents are present on the opposite side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Answer 8

Expert Solution

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 1

Figure 1

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 2

Figure 2

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. Therefore, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer 13

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Answer 14

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 1

Figure 1

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 2

Figure 2

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. Therefore, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Answer 15

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl but−2−ynedioate.

Answer 16

Expert Solution

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 3

Figure 3

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 4

Figure 4

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on same sides. Therefore, both the substituents are present on the same side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer 21

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Answer 22

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 3

Figure 3

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 4

Figure 4

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on same sides. Therefore, both the substituents are present on the same side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Answer 23

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Answer 24

Expert Solution

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 5

Figure 5

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 6

Figure 6

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on opposite sides. Therefore, both the substituents are present on the opposite side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Conclusion

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are to be predicted.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile. In this type of reaction, syn addition takes place.

Answer 29

Answer to Problem 27.41P

The starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.

Answer 30

Explanation of Solution

The given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 5

Figure 5

Retro synthesis can be carried out to identify the diene and dienophile for the given product.

The reaction that shows the disconnection approach of the given product is shown below.

Organic Chemistry, Chapter 27, Problem 27.41P , additional homework tip 6

Figure 6

In the given product, the ring is opened due to the rearrangement of π bonds as shown in the above diagram. This results in the formation of diene and dienophile. The above diagram shows that the substituents (COOCH3) attached to the dienophile are on opposite sides. Therefore, both the substituents are present on the opposite side of the product as well.

Thus, the starting materials that are needed to synthesize the given compound by a thermal [4+2] cycloaddition are octa−3,5−diene and dimethyl maleate.