ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
6th Edition
ISBN: 9781266633973
Author: SMITH
Publisher: MCG
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Chapter 26.9, Problem 23P
Interpretation Introduction

(a)

Interpretation: The given aldose is oxidized to optically inactive aldaric acid or not is to be identified.

Concept introduction: The aldehyde group and primary alcohol of aldoses oxidizes to carboxyl groups on treatment with warm HNO3. The oxidation of aldoses leads to the formation of aldaric acid.

Interpretation Introduction

(b)

Interpretation: The given aldose is oxidized to optically inactive aldaric acid or not is to be identified.

Concept introduction: The aldehyde group and primary alcohol of aldoses oxidizes to carboxyl groups on treatment with warm HNO3. The oxidation of aldoses leads to the formation of aldaric acid.

Interpretation Introduction

(c)

Interpretation: The given aldose is oxidized to optically inactive aldaric acid or not is to be identified.

Concept introduction: The aldehyde group and primary alcohol of aldoses oxidizes to carboxyl groups on treatment with warm HNO3. The oxidation of aldoses leads to the formation of aldaric acid.

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4. Read paragraph 4.15 from your textbook, use your calculated lattice energy values for CuO, CuCO3 and Cu(OH)2 an explain thermal decomposition reaction of malachite: Cu2CO3(OH)2 →2CuO + H2O + CO2 (3 points)

Chapter 26 Solutions

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