ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Chapter 26.7B, Problem 26.14P
Interpretation Introduction

Interpretation:

The structure of Kodel polyester that is formed by transesterification of dimethyl terephthalate with 1,4-di(hydroxymethyl)cyclohexane is to be drawn.

Concept introduction:

Transesterification process results in the formation of different ester and alcohol by the reaction between the alcohol and ester present as reactant. In this process strong acids catalyse the reaction by donation a proton to the carbonyl group, results in the formation of more potent electrophile and the bases catalyse the reaction removes the proton from the alcohol, results in the formation of more nucleophilic.

Polyesters are the polymers that consist of ester functional group in the main polymer chain. Kodel is type of polyester used in the manufacture of thread.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br
The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;
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