ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Chapter 26.2A, Problem 26.2P
Interpretation Introduction

Interpretation: The mechanism for polymerisation of propylene in the presence of benzoyl peroxide is to be proposed.

Concept Introduction: Free radical polymerisation is the polymerisation in which polymer forms through free radical mechanism in which electrons are equally distributed between both atoms involved in bonding. The polymerisation occurs in the presence of benzoyl peroxide is the free radical polymerisation.

To determine: The mechanism for given polymerisation reaction.

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Assign ALL signals for the proton and carbon NMR spectra on the following pages.
7.5 1.93 2.05 C B A 4 3 5 The Joh. 9 7 8 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 0.86 OH 10 4 3 5 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 CI 4 3 5 1 2 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 2.21 4.00 1.5 2.00 2.07 1.0 ppm 2.76
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