Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
3rd Edition
ISBN: 9781119340577
Author: Klein
Publisher: Wiley (WileyPLUS Products)
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Question
Chapter 26.6, Problem 23CC
Interpretation Introduction
Interpretation:
Glycerol can cross the cell membrane or not has to be explained.
Concept introduction:
Steroids are organic compounds which has four rings that are arranged in a specific molecular configuration. A steroid contains four rings out of which three are six-membered ring and the other one is a five-membered ring. The skeleton of steroid can be shown as,
Anabolic steroids are a class of steroids that promote growth of muscle by mimicking the tissue building effect of testosterone.
To identify: the given compounds as anabolic steroid or oral contraceptive based on their structures.
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CH3
CH
H3C
CH3
H
OH
H3C-
-OCH2CH3
H3C
H
-OCH3
For each of the above compounds, do the following:
1. List the wave numbers of all the IR bands in the 1350-4000 cm-1 region.
For each one, state what bond or group it represents.
2. Label equivalent sets of protons with lower-case letters. Then, for each 1H NMR
signal, give the 8 value, the type of splitting (singlet, doublet etc.), and the number
protons it represents.
of
letter
δ value
splitting
# of protons
3. Redraw the compound and label equivalent sets of carbons with lower-case
letters.
Then for each set of carbons give the 5 value and # of carbons it represents.
letter
δ value
# of carbons
Draw the correct ionic form(s) of arginine at the pKa and PI in your titration curve. Use your titration curve to help you determine which form(s) to draw out.
Chapter 26 Solutions
Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
Ch. 26.2 - Prob. 1CCCh. 26.2 - Prob. 2CCCh. 26.3 - Prob. 1LTSCh. 26.3 - Prob. 3PTSCh. 26.3 - Prob. 4ATSCh. 26.3 - Prob. 5ATSCh. 26.3 - Prob. 6ATSCh. 26.4 - Prob. 7CCCh. 26.4 - Prob. 8CCCh. 26.4 - Prob. 2LTS
Ch. 26.4 - Prob. 9PTSCh. 26.4 - Prob. 10ATSCh. 26.4 - Prob. 11ATSCh. 26.4 - Prob. 3LTSCh. 26.4 - Prob. 12PTSCh. 26.4 - Prob. 13LTSCh. 26.4 - Prob. 14LTSCh. 26.5 - Prob. 15CCCh. 26.5 - Prob. 16CCCh. 26.5 - Prob. 17CCCh. 26.5 - Prob. 18CCCh. 26.5 - Prob. 19CCCh. 26.6 - Prob. 20CCCh. 26.6 - Prob. 21CCCh. 26.6 - Prob. 22CCCh. 26.6 - Prob. 23CCCh. 26.7 - Prob. 24CCCh. 26.8 - Prob. 4LTSCh. 26.8 - Prob. 25PTSCh. 26.8 - Prob. 26ATSCh. 26.8 - Prob. 27CCCh. 26.8 - Prob. 28CCCh. 26 - Prob. 29PPCh. 26 - Prob. 30PPCh. 26 - Draw two different cephalins that contain one...Ch. 26 - Prob. 32PPCh. 26 - Prob. 33PPCh. 26 - Prob. 34PPCh. 26 - Prob. 35PPCh. 26 - Prob. 36PPCh. 26 - Prob. 37PPCh. 26 - Prob. 38PPCh. 26 - Prob. 39PPCh. 26 - Prob. 40PPCh. 26 - Prob. 41PPCh. 26 - Prob. 42PPCh. 26 - Prob. 43PPCh. 26 - Prob. 44PPCh. 26 - Prob. 45PPCh. 26 - Prob. 46PPCh. 26 - Prob. 47PPCh. 26 - Prob. 48PPCh. 26 - Prob. 49PPCh. 26 - Prob. 50PPCh. 26 - Prob. 51IPCh. 26 - Prob. 52IPCh. 26 - Prob. 53IPCh. 26 - Prob. 54IPCh. 26 - Prob. 55IPCh. 26 - Prob. 56CPCh. 26 - Prob. 57CP
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