Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
3rd Edition
ISBN: 9781119340577
Author: Klein
Publisher: Wiley (WileyPLUS Products)
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Chapter 26.6, Problem 23CC
Interpretation Introduction

Interpretation:

Glycerol can cross the cell membrane or not has to be explained.

Concept introduction:

Steroids are organic compounds which has four rings that are arranged in a specific molecular configuration.  A steroid contains four rings out of which three are six-membered ring and the other one is a five-membered ring.  The skeleton of steroid can be shown as,

Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion, Chapter 26.6, Problem 23CC

Anabolic steroids are a class of steroids that promote growth of muscle by mimicking the tissue building effect of testosterone.

To identify: the given compounds as anabolic steroid or oral contraceptive based on their structures.

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…
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