Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed. Concept introduction: Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues. But in phosphoglyceride one of the fatty acid residue in triglyceride is replaced by a phosphoester. Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate. To draw : the structure of lecithin

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Answer 1

Question

Chapter 26.5, Problem 15CC

(a)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept introduction:

Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues. But in phosphoglyceride one of the fatty acid residue in triglyceride is replaced by a phosphoester. Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate.

To draw: the structure of lecithin

(b)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory.

(c)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory. If the carbon is not attached to four different groups means then it is said to be achiral.

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Assign ALL signals for the proton and carbon NMR spectra on the following pages.

7.5 1.93 2.05 C B A 4 3 5 The Joh. 9 7 8 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 0.86 OH 10 4 3 5 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 CI 4 3 5 1 2 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 2.21 4.00 1.5 2.00 2.07 1.0 ppm 2.76

Assign the functional group bands on the IR spectra.

Answer 2

Question

Chapter 26.5, Problem 15CC

(a)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept introduction:

Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues. But in phosphoglyceride one of the fatty acid residue in triglyceride is replaced by a phosphoester. Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate.

To draw: the structure of lecithin

(b)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory.

(c)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory. If the carbon is not attached to four different groups means then it is said to be achiral.

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Answer 3

Question

Chapter 26.5, Problem 15CC

(a)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept introduction:

Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues. But in phosphoglyceride one of the fatty acid residue in triglyceride is replaced by a phosphoester. Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate.

To draw: the structure of lecithin

(b)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory.

(c)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory. If the carbon is not attached to four different groups means then it is said to be achiral.

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Answer 4

Question

Chapter 26.5, Problem 15CC

(a)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept introduction:

Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues. But in phosphoglyceride one of the fatty acid residue in triglyceride is replaced by a phosphoester. Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate.

To draw: the structure of lecithin

(b)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory.

(c)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory. If the carbon is not attached to four different groups means then it is said to be achiral.

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Answer 5

Chapter 26.5, Problem 15CC

(a)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept introduction:

Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues. But in phosphoglyceride one of the fatty acid residue in triglyceride is replaced by a phosphoester. Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate.

To draw: the structure of lecithin

(b)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory.

(c)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory. If the carbon is not attached to four different groups means then it is said to be achiral.

Answer 6

Chapter 26.5, Problem 15CC

(a)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept introduction:

Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues. But in phosphoglyceride one of the fatty acid residue in triglyceride is replaced by a phosphoester. Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate.

To draw: the structure of lecithin

Answer 7

Chapter 26.5, Problem 15CC

(a)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept introduction:

Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues. But in phosphoglyceride one of the fatty acid residue in triglyceride is replaced by a phosphoester. Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate.

To draw: the structure of lecithin

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory. If the carbon is not attached to four different groups means then it is said to be achiral.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structure of lecithin and the naturally occurring enantiomer need to be drawn and if phosphodiester is in C2 position will there be chirality has to be discussed.

Concept Introduction:

Chirality is the ability of the compound to rotate the plane polarized light when it is passed through them. A chiral center is the one when the carbon atom is attached to a four different groups. If the plane polarized light is rotated clockwise then the compound is said to be dextrorotatory and if it is anti-clockwise then the compound is levorotatory. If the carbon is not attached to four different groups means then it is said to be achiral.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 26.2 - Prob. 1CC Ch. 26.2 - Prob. 2CC Ch. 26.3 - Prob. 1LTS Ch. 26.3 - Prob. 3PTS Ch. 26.4 - Prob. 7CC Ch. 26.4 - Prob. 8CC Ch. 26.4 - Prob. 2LTS Ch. 26.4 - Prob. 9PTS Ch. 26.4 - Prob. 3LTS Ch. 26.4 - Prob. 12PTS

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Chapter 26 Solutions