EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Question
Chapter 26, Problem 42PP
Interpretation Introduction
Interpretation:
Compound structure has to be drawn when alcohol with 30 carbon atoms and
Concept introduction:
Hydrolysis is a process in which the ester is converted to its respective carboxylic acid and alcohol in presence of aqueous acid or base.
Esterification is a reaction when an alcohol and a carboxylic acid react together in presence of aqueous acid or base to form an ester. The general scheme can be shown as,
Esterification is the reverse of hydrolysis
To draw: the compound taken when the given carboxylic acid and alcohol are obtained when treated with aqueous sodium hydroxide.
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Assign ALL signals for the proton and carbon NMR spectra on the following pages.
7.5
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2.05
C
B
A
4
3
5
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9
7
8
1
2
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
2.5
2.0
1.5
1.0 ppm
9
7
8
0.86
OH 10
4
3
5
1
2
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
2.5
2.0
1.5
1.0
ppm
9
7
8
CI
4
3
5
1
2
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
2.5
2.0
2.21
4.00
1.5
2.00
2.07
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2.76
Assign the functional group bands on the IR spectra.
Chapter 26 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 26.2 - Prob. 1CCCh. 26.2 - Prob. 2CCCh. 26.3 - Prob. 1LTSCh. 26.3 - Prob. 3PTSCh. 26.4 - Prob. 7CCCh. 26.4 - Prob. 8CCCh. 26.4 - Prob. 2LTSCh. 26.4 - Prob. 9PTSCh. 26.4 - Prob. 3LTSCh. 26.4 - Prob. 12PTS
Ch. 26.5 - Prob. 15CCCh. 26.5 - Prob. 16CCCh. 26.5 - Prob. 17CCCh. 26.5 - Prob. 18CCCh. 26.5 - Prob. 19CCCh. 26.6 - Prob. 20CCCh. 26.6 - Prob. 21CCCh. 26.6 - Prob. 22CCCh. 26.6 - Prob. 23CCCh. 26.7 - Prob. 24CCCh. 26.8 - Prob. 4LTSCh. 26.8 - Prob. 25PTSCh. 26.8 - Prob. 27CCCh. 26.8 - Prob. 28CCCh. 26 - Prob. 29PPCh. 26 - Prob. 30PPCh. 26 - Prob. 32PPCh. 26 - Prob. 33PPCh. 26 - Prob. 34PPCh. 26 - Prob. 35PPCh. 26 - Prob. 36PPCh. 26 - Prob. 37PPCh. 26 - Prob. 38PPCh. 26 - Prob. 39PPCh. 26 - Prob. 40PPCh. 26 - Prob. 41PPCh. 26 - Prob. 42PPCh. 26 - Prob. 43PPCh. 26 - Prob. 44PPCh. 26 - Prob. 45PPCh. 26 - Prob. 46PPCh. 26 - Prob. 47PPCh. 26 - Prob. 48PPCh. 26 - Prob. 49PPCh. 26 - Prob. 50PP
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