(a) Interpretation: The structure of ketotetrose is to be drawn. Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26.2, Problem 1P

Interpretation Introduction

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

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Draw the structure of (a) a ketotetrose; (b) an aldopentose; (c) an aldotetrose.

Draw the structure of: (a) a polysaccharide formed by joining D-mannose units in 1->4-ß-glycosidic linkages; (b) a polysaccharide formed by joining D-glucose units in 1->6-a-glycosidic linkages. The polysaccharide in (b) is dextran, a component of dental plaque.

A) Define "reducing sugar." (b) Sucrose is a disaccharide composed of glucose and fructose (Glc(1 → 2)Fru). Explain why sucrose is not a reducing sugar, even though both glucose and fructose are.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26.2, Problem 1P

Interpretation Introduction

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26.2, Problem 1P

Interpretation Introduction

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26.2, Problem 1P

Interpretation Introduction

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

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Answer 5

Chapter 26.2, Problem 1P

Interpretation Introduction

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Interpretation Introduction

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Answer 6

Chapter 26.2, Problem 1P

Interpretation Introduction

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Answer 7

Chapter 26.2, Problem 1P

Interpretation Introduction

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Answer 8

Interpretation Introduction

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Answer 9

Interpretation Introduction

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Answer 10

Interpretation Introduction

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Answer 11

Interpretation Introduction

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 26.2 - Prob. 1P Ch. 26.2 - Prob. 2P Ch. 26.2 - Label each stereogenic center as R or S. a. b. c....Ch. 26.2 - Convert the ball-and-stick model to a Fischer...Ch. 26.2 - Prob. 5P Ch. 26.2 - Prob. 6P Ch. 26.3 - Prob. 7P Ch. 26.3 - Prob. 8P Ch. 26.4 - Prob. 9P Ch. 26.4 - Prob. 10P

(a) Interpretation: The structure of ketotetrose is to be drawn. Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Concept explainers

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

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Chapter 26 Solutions

(a) Interpretation: The structure of ketotetrose is to be drawn. Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Concept explainers

(a) Interpretation: The structure of ketotetrose is to be drawn. Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

(b) Interpretation: The structure of aldopentose is to be drawn. Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

(c) Interpretation: The structure of aldotetrose is to be drawn. Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

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Chapter 26 Solutions

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.