Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
7th Edition
ISBN: 9780134240152
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 26.12, Problem 18P
Which of the following base sequences is most likely to be recognized by a restriction endonuclease?
A ACGGGT
B ACGCGT
C ACGGCA
D ACACGT
E ACATCGT
F CCAACC
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12. Mark the correct statement about
reactions a and b :
a.
Br
+ -OH
Br
b.
+ Br
H₂O
+
Br
-OH
+
H₂O
A) The reactions are elimination
reactions, with reaction "a" being of type
E2 and reaction "b" being of type E1.
B) Reaction "a" is an E2 type elimination
occurring in one step and reaction "b" is
an SN1 type substitution.
C) Both reactions can result in the
formation of carbocation, but in reaction
"b" the most stable carbocation will be
formed.
D) Both reactions occur at the same rate
○ and have the same number of reaction
steps.
E) Reaction "b" is an E2 type elimination
occurring in two steps and reaction "a" is
an SN2 type substitution.
Chloroform, long used as an anesthetic and now considered carcinogenic, has a heat of vaporization of 31.4 kJ/mol. During vaporization, its entropy increases by 94.2 J/mol.K. Therefore, select the alternative that indicates the temperature, in degrees Celsius, at which chloroform begins to boil under a pressure of 1 atm.
A) 28
B) 40
C) 52
D) 60
E) 72
If we assume a system with an anodic overpotential, the variation of n as a function
of current density:
1. at low fields is linear 2. at higher fields, it follows Tafel's law
Obtain the range of current densities for which the overpotential has the same value
when calculated for 1 and 2 cases (maximum relative difference of 5% compared to
the behavior for higher fields).
To which overpotential range does this correspond?
Data: i = 1.5 mA cm², T = 300°C, B = 0.64, R = 8.314 J K1 mol-1 and F = 96485 C mol-1.
Chapter 26 Solutions
Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
Ch. 26.1 - In acidic solutions, nucleosides are hydrolyzed to...Ch. 26.1 - Draw the structure for each of the following: a....Ch. 26.2 - Prob. 3PCh. 26.3 - Indicate whether each functional group of the five...Ch. 26.3 - Prob. 5PCh. 26.3 - If one of the strands of DNA has the following...Ch. 26.4 - The 2',3-cyclic phosphodiester that is formed...Ch. 26.5 - Using a dark line for the original parental DNA...Ch. 26.7 - Why do both thymine and uracil specify the...Ch. 26.9 - If methionine is always the first amino acid...
Ch. 26.9 - Four Cs occur in a row in the segment of mRNA...Ch. 26.9 - UAA is a stop codon. Why does the UAA sequence in...Ch. 26.9 - Prob. 13PCh. 26.9 - Write the sequences of bases in the sense strand...Ch. 26.9 - List the possible codons on mRNA that speciy each...Ch. 26.10 - Adenine can be deaminated to hypoxanthine, and...Ch. 26.10 - Explain why thymine cannot be deaminated.Ch. 26.12 - Which of the following base sequences is most...Ch. 26 - Name the following:Ch. 26 - What nonapeptide is coded for by the following...Ch. 26 - What is the sequence of bases in the template...Ch. 26 - Prob. 22PCh. 26 - Prob. 23PCh. 26 - Prob. 24PCh. 26 - Propose a mechanism for the following reaction:Ch. 26 - A segment of DNA has 18 base pairs. It has 7...Ch. 26 - Match the codon with the anticodon:Ch. 26 - Prob. 28PCh. 26 - Which of the following pairs of dinucleotides are...Ch. 26 - Human immunodeficiency virus (HIV) is the...Ch. 26 - If a mRNA contained only U and G in random...Ch. 26 - Why is the codon a triplet rather than a doublet...Ch. 26 - RNAase, the enzyme that catalyzes the hydrolysis...Ch. 26 - The amino acid sequences of peptide fragments...Ch. 26 - Which cytosine in the following sense strand of...Ch. 26 - Prob. 36PCh. 26 - Sodium nitrite, a common food preservative (page...Ch. 26 - Why does DNA not unravel completely before...Ch. 26 - Staphylococcus nuclease is an enzyme that...Ch. 26 - The first amino acid incorporated into a...
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