ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
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Chapter 26, Problem 37P
Sodium nitrite, a common food preservative (page 906), is capable of causing mutations in an acidic environment by converting cytosines to uracils. Explain how this occurs.
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According to open access forums ionic antimony Sb (111) can be reduced to elemental Sb (0) in solution and in macromolecules like condensation polymers polyethylene terephthalate (PET) causing greying of the polymer matrix. It has been connected to thermal degradation of the polymer during processing to the formation of thermally unstable EG ethyleen glycol that forms at various temperatures formic acid, formaldehyde, acetaldehyde and much more depending on temperature. I need to know what organics are more powerful reducing agents and at what concentration (relative) to each organic will initiate this reduction. Furthermore, is the pH dependant ? Are other trace elements in the plastic also a cause of concern e.g. aluminum from aluminum chloride (lewis acid). Therefore, the ultimate solution should include a means to inhibit reduction of ionic antimony and will the same solution comply with cobalt impurities from ionic cobalt? Some PET have combinations of catalyst and their residues…
Chapter 26 Solutions
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
Ch. 26.1 - In acidic solutions, nucleosides are hydrolyzed to...Ch. 26.1 - Draw the structure for each of the following: a....Ch. 26.3 - Indicate whether each functional group of the five...Ch. 26.3 - Prob. 4PCh. 26.3 - If one of the strands of DNA has the following...Ch. 26.4 - The 2',3-cyclic phosphodiester that is formed...Ch. 26.5 - Using a dark line for the original parental DNA...Ch. 26.7 - Why do both thymine and uracil specify the...Ch. 26.9 - If methionine is always the first amino acid...Ch. 26.9 - Four Cs occur in a row in the segment of mRNA...
Ch. 26.9 - UAA is a stop codon. Why does the UAA sequence in...Ch. 26.9 - Prob. 12PCh. 26.9 - Write the sequences of bases in the sense strand...Ch. 26.9 - List the possible codons on mRNA that speciy each...Ch. 26.10 - Adenine can be deaminated to hypoxanthine, and...Ch. 26.10 - Explain why thymine cannot be deaminated.Ch. 26.12 - Which of the following base sequences is most...Ch. 26 - What nonapeptide is coded for by the following...Ch. 26 - What is the sequence of bases in the template...Ch. 26 - Prob. 20PCh. 26 - A segment of DNA has 18 base pairs. It has 7...Ch. 26 - Name the following:Ch. 26 - Prob. 23PCh. 26 - Propose a mechanism for the following reaction:Ch. 26 - The first amino acid incorporated into a...Ch. 26 - Match the codon with the anticodon:Ch. 26 - a. Using the single-letter abbreviations for the...Ch. 26 - Which of the following pairs of dinucleotides are...Ch. 26 - Human immunodeficiency virus (HIV) is the...Ch. 26 - If a mRNA contained only U and G in random...Ch. 26 - Why is the codon a triplet rather than a doublet...Ch. 26 - RNAase, the enzyme that catalyzes the hydrolysis...Ch. 26 - The amino acid sequences of peptide fragments...Ch. 26 - Which cytosine in the following sense strand of...Ch. 26 - Prob. 36PCh. 26 - Sodium nitrite, a common food preservative (page...Ch. 26 - Why does DNA not unravel completely before...Ch. 26 - Staphylococcus nuclease is an enzyme that...
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- From a pH standpoint is the reduction of ionic Antimony Sb (111) to elemental Sb (0) occur more readily by acidic species acting as reducing agents or basic substances? I want to inhibit this reduction of ionic to elemental. Suggestions and directions!arrow_forwardObtain the standard potential at 25°C of the Cu* I Cu | Pt electrode from the standard potentials E° Cu²+/Cu = 0.341 V and E Cu²+ /Cu+ = 0.153 V.arrow_forwardState two variables on which the transport number in electrochemistry depends.arrow_forward
- please solvearrow_forwardplease help with synthesisarrow_forward10. Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the following compound. In order to recieve full credit, you MUST SHOW YOUR WORK! H₂N CI OH CI カー 11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign R/S configurations for all stereoisomers and indicate the relationship between each as enantiomer, diastereomer, or meso. NH2 H HNH, -18arrow_forward
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