Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
3rd Edition
ISBN: 9781119320524
Author: Klein
Publisher: WILEY
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Chapter 26, Problem 32PP
Interpretation Introduction

Interpretation:

Structure of optically inactive triglyceride need to be drawn from the given glycerol, one equivalent of palmitic acid and two equivalents of myristic acid and also to check whether the formed triglyceride will react with molecular hydrogen.

Concept introduction:

Esterification is a process in which the carboxylic acid and an alcohol react to form a ester bond.  This can take place in presence of acid or base.  The bond is formed due to loss of water molecule when the condensation reaction takes place.  Simply to say esterification is the reverse process of hydrolysis.

Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy, Chapter 26, Problem 32PP

From the above scheme we can find out the starting triglyceride considering the fatty acid and glycerol.

Molecular hydrogen will react with unsaturated compounds to reduce them.  If the compound does not have any unsaturation then that compound wont react with molecular hydrogen.

To draw: the structure of optically active triglyceride from the given problem statement.

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• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak
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