EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
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Chapter 26, Problem 30PP
Interpretation Introduction

Interpretation:

Two possible structures of cephalin need to be drawn and to discuss whether the compounds are chiral.

Concept introduction:

Phosphoglycerides are same as triglycerides but the only difference is that in triglycerides there are three fatty acid residues.  But in phosphoglyceride one of the fatty acid residues in triglyceride is replaced by a phosphoester.  Hydrolysis of phosphoglycerides yield glycerol, fatty acid, phosphate.

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 26, Problem 30PP

To draw: the two possible structure of cephalins and check whether both are chiral.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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