ORGANIC CHEM PRINT STUDY GDE & SSM
4th Edition
ISBN: 9781119810650
Author: Klein
Publisher: WILEY
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Question
Chapter 26, Problem 29PP
a)
Interpretation Introduction
Interpretation:
The products need to be predicted when tripalmitolein is treated with the given set of reagents.
Concept introduction:
Reduction is a reaction in which hydrogen is added to the given compound. One of the examples is conversion of unsaturated bonds to saturated bonds.
To predict: the product formed when tripalmitolein is treated with excess hydrogen and nickel.
a)
Expert Solution
Answer to Problem 29PP
Solution:
The product predicted when tripalmitolein is treated with hydrogen and nickel is,
Explanation of Solution
Structure of tripalmitolein
The structure of tripalmitolein is drawn as above. In tripalmitolein there are three double bonds.
Reaction with excess hydrogen and nickel.
When tripalmitolein is treated with excess hydrogen and nickel, all the double bonds present in the fatty acid residue are reduced to saturated bonds to give a saturated triglyceride as shown above.
Conclusion
The product formed when tripalmitolein undergoes reaction with excess hydrogen and nickel is a saturated triglyceride and the structure is,
(b)
Interpretation Introduction
Interpretation:
The products need to be predicted when tripalmitolein is treated with the given set of reagents.
Concept introduction:
When triglyceride is treated with aqueous sodium hydroxide, the ester group is hydrolyzed to give glycerol and the fatty acid as carboxylate ion.
To predict: the product formed when tripalmitolein is treated with aqueous sodium hydroxide.
(b)
Expert Solution
Answer to Problem 29PP
Answer
The product obtained when tripalmitolein is treated with aqueous base is,
Explanation of Solution
Structure of tripalmitolein
The structure of tripalmitolein is drawn as above. In tripalmitolein there are three ester groups.
Reaction with excess hydrogen and nickel.
When tripalmitolein is treated with aqueous sodium hydroxide the ester group is hydrolyzed to form glycerol and fatty acid carboxylate ion.
Conclusion
The product formed when tripalmitolein is treated with aqueous sodium hydroxide is glycerol and three equivalents of carboxylate ion,
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Using the general properties of equilibrium constants
At a certain temperature, the equilibrium constant K for the following reaction is 1.3 × 10 4:
Cl2(g) + CHCl3(g) HCl(g) + CC₁(g)
Use this information to complete the following table.
Suppose a 16. L reaction vessel is filled with 1.6 mol of HCI and
1.6 mol of CCl4. What can you say about the composition of the
mixture in the vessel at equilibrium?
There will be very little Cl2 and CHCl3.
☐ x10
There will be very little HCI and CCl4.
Neither of the above is true.
What is the equilibrium constant for the following reaction? Be
sure your answer has the correct number of significant digits.
HCl(g)+CC14(g)
12
Cl2(9)+CHCl3(9)
K = 0 ☐
What is the equilibrium constant for the following reaction? Be
sure your answer has the correct number of significant digits.
2 Cl₂(9)+2CHCl3(9)
2 HCl(9)+2CC₁₁(9)
K =
✓
00.
18
Ar
Chapter 26 Solutions
ORGANIC CHEM PRINT STUDY GDE & SSM
Ch. 26.2 - Prob. 1CCCh. 26.2 - Prob. 2CCCh. 26.3 - Prob. 1LTSCh. 26.3 - Prob. 3PTSCh. 26.4 - Prob. 7CCCh. 26.4 - Prob. 8CCCh. 26.4 - Prob. 2LTSCh. 26.4 - Prob. 9PTSCh. 26.4 - Prob. 3LTSCh. 26.4 - Prob. 12PTS
Ch. 26.5 - Prob. 15CCCh. 26.5 - Prob. 16CCCh. 26.5 - Prob. 17CCCh. 26.5 - Prob. 18CCCh. 26.5 - Prob. 19CCCh. 26.6 - Prob. 20CCCh. 26.6 - Prob. 21CCCh. 26.6 - Prob. 22CCCh. 26.6 - Prob. 23CCCh. 26.7 - Prob. 24CCCh. 26.8 - Prob. 4LTSCh. 26.8 - Prob. 25PTSCh. 26.8 - Prob. 27CCCh. 26.8 - Prob. 28CCCh. 26 - Prob. 29PPCh. 26 - Prob. 30PPCh. 26 - Prob. 32PPCh. 26 - Prob. 33PPCh. 26 - Prob. 34PPCh. 26 - Prob. 35PPCh. 26 - Prob. 36PPCh. 26 - Prob. 37PPCh. 26 - Prob. 38PPCh. 26 - Prob. 39PPCh. 26 - Prob. 40PPCh. 26 - Prob. 41PPCh. 26 - Prob. 42PPCh. 26 - Prob. 43PPCh. 26 - Prob. 44PPCh. 26 - Prob. 45PPCh. 26 - Prob. 46PPCh. 26 - Prob. 47PPCh. 26 - Prob. 48PPCh. 26 - Prob. 49PPCh. 26 - Prob. 50PP
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