(a) Interpretation: The given reaction is to be completed and product formed is to be stated. Concept Introduction: The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Nitration reaction is an electrophilic aromatic substitution reaction. In this reaction nitronium ion acts as the electrophile. Nitronium ion is a very strong electrophile.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26, Problem 26.9P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Nitration reaction is an electrophilic aromatic substitution reaction. In this reaction nitronium ion acts as the electrophile. Nitronium ion is a very strong electrophile.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Acetic anhydride also gives electrophilic substitution reaction. The furan has C-2 and C-5 carbons which are activated for electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

Aldol condensation reaction takes place in the carbonyl compounds which contains α−

hydrogen atom. The condensation reaction takes place between enolate ion and carbonyl compound to form a β-hydroxy carbonyl compound. Aldol condensation reaction takes place in the presence of base.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

N-bromosuccinamide is a brominating agent. It gives electrophilic substitution and radical substitution reaction. In the presence of light radical substitution takes place and in presence of heat electrophilic substitution takes place. N-bromosuccinamide is a very good source of bromine radical.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26, Problem 26.9P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Nitration reaction is an electrophilic aromatic substitution reaction. In this reaction nitronium ion acts as the electrophile. Nitronium ion is a very strong electrophile.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Acetic anhydride also gives electrophilic substitution reaction. The furan has C-2 and C-5 carbons which are activated for electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

Aldol condensation reaction takes place in the carbonyl compounds which contains α−

hydrogen atom. The condensation reaction takes place between enolate ion and carbonyl compound to form a β-hydroxy carbonyl compound. Aldol condensation reaction takes place in the presence of base.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

N-bromosuccinamide is a brominating agent. It gives electrophilic substitution and radical substitution reaction. In the presence of light radical substitution takes place and in presence of heat electrophilic substitution takes place. N-bromosuccinamide is a very good source of bromine radical.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26, Problem 26.9P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Nitration reaction is an electrophilic aromatic substitution reaction. In this reaction nitronium ion acts as the electrophile. Nitronium ion is a very strong electrophile.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Acetic anhydride also gives electrophilic substitution reaction. The furan has C-2 and C-5 carbons which are activated for electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

Aldol condensation reaction takes place in the carbonyl compounds which contains α−

hydrogen atom. The condensation reaction takes place between enolate ion and carbonyl compound to form a β-hydroxy carbonyl compound. Aldol condensation reaction takes place in the presence of base.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

N-bromosuccinamide is a brominating agent. It gives electrophilic substitution and radical substitution reaction. In the presence of light radical substitution takes place and in presence of heat electrophilic substitution takes place. N-bromosuccinamide is a very good source of bromine radical.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26, Problem 26.9P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Nitration reaction is an electrophilic aromatic substitution reaction. In this reaction nitronium ion acts as the electrophile. Nitronium ion is a very strong electrophile.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Acetic anhydride also gives electrophilic substitution reaction. The furan has C-2 and C-5 carbons which are activated for electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

Aldol condensation reaction takes place in the carbonyl compounds which contains α−

hydrogen atom. The condensation reaction takes place between enolate ion and carbonyl compound to form a β-hydroxy carbonyl compound. Aldol condensation reaction takes place in the presence of base.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

N-bromosuccinamide is a brominating agent. It gives electrophilic substitution and radical substitution reaction. In the presence of light radical substitution takes place and in presence of heat electrophilic substitution takes place. N-bromosuccinamide is a very good source of bromine radical.

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Answer 5

Chapter 26, Problem 26.9P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Nitration reaction is an electrophilic aromatic substitution reaction. In this reaction nitronium ion acts as the electrophile. Nitronium ion is a very strong electrophile.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Acetic anhydride also gives electrophilic substitution reaction. The furan has C-2 and C-5 carbons which are activated for electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

Aldol condensation reaction takes place in the carbonyl compounds which contains α−

hydrogen atom. The condensation reaction takes place between enolate ion and carbonyl compound to form a β-hydroxy carbonyl compound. Aldol condensation reaction takes place in the presence of base.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

N-bromosuccinamide is a brominating agent. It gives electrophilic substitution and radical substitution reaction. In the presence of light radical substitution takes place and in presence of heat electrophilic substitution takes place. N-bromosuccinamide is a very good source of bromine radical.

Answer 6

Chapter 26, Problem 26.9P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Nitration reaction is an electrophilic aromatic substitution reaction. In this reaction nitronium ion acts as the electrophile. Nitronium ion is a very strong electrophile.

Answer 7

Chapter 26, Problem 26.9P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Nitration reaction is an electrophilic aromatic substitution reaction. In this reaction nitronium ion acts as the electrophile. Nitronium ion is a very strong electrophile.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Acetic anhydride also gives electrophilic substitution reaction. The furan has C-2 and C-5 carbons which are activated for electrophilic aromatic substitution reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

The reaction in which an atom of aromatic system is replaced by an electrophile is known as electrophilic aromatic substitution reaction. Acetic anhydride also gives electrophilic substitution reaction. The furan has C-2 and C-5 carbons which are activated for electrophilic aromatic substitution reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

Aldol condensation reaction takes place in the carbonyl compounds which contains α−

hydrogen atom. The condensation reaction takes place between enolate ion and carbonyl compound to form a β-hydroxy carbonyl compound. Aldol condensation reaction takes place in the presence of base.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

Aldol condensation reaction takes place in the carbonyl compounds which contains α−

hydrogen atom. The condensation reaction takes place between enolate ion and carbonyl compound to form a β-hydroxy carbonyl compound. Aldol condensation reaction takes place in the presence of base.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

N-bromosuccinamide is a brominating agent. It gives electrophilic substitution and radical substitution reaction. In the presence of light radical substitution takes place and in presence of heat electrophilic substitution takes place. N-bromosuccinamide is a very good source of bromine radical.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed and product formed is to be stated.

Concept Introduction:

N-bromosuccinamide is a brominating agent. It gives electrophilic substitution and radical substitution reaction. In the presence of light radical substitution takes place and in presence of heat electrophilic substitution takes place. N-bromosuccinamide is a very good source of bromine radical.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author explains electrophilic aromatic substitution reaction, nitration reaction and acetic anhydride.

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Chapter 26 Solutions