PKG ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259963667
Author: SMITH
Publisher: MCG
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Chapter 26, Problem 26.43P
Devise a synthesis of each compound using a Heck reaction as one step. You may use benzene,
a. 
b. 
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Devise a synthesis of each compound using 1-bromobutane (CH3CH2CH2CH2Br) as the only organic starting material. You may use any other inorganic reagents.
Devise a synthesis of each compound from benzene. You may also use any organic compounds having four or fewer carbons and any required inorganic reagents.
Devise a synthesis of each compound using 1-bromobutane(CH3CH2CH2CH2Br) as the only organic starting material. You may useany other inorganic reagents.
Chapter 26 Solutions
PKG ORGANIC CHEMISTRY
Ch. 26 - Prob. 26.1PCh. 26 - Prob. 26.2PCh. 26 - Prob. 26.3PCh. 26 - Prob. 26.4PCh. 26 - Prob. 26.5PCh. 26 - Prob. 26.6PCh. 26 - Prob. 26.7PCh. 26 - Problem 26.8
What starting materials are needed to...Ch. 26 - Prob. 26.9PCh. 26 - Problem 26.10
What reagents are needed to convert...
Ch. 26 - Problem 26.11
What product is formed when each...Ch. 26 - Prob. 26.12PCh. 26 - Problem 26.13
Draw the products formed when each...Ch. 26 - Problem 26.14
What products are formed when ...Ch. 26 - Problem 26.15
Draw the product formed from...Ch. 26 -
What product is formed by ring-closing metathesis...Ch. 26 - Problem 26.17
What starting material is needed to...Ch. 26 - 26.18 In addition to organic halides, alkyl...Ch. 26 - 26.19 What product is formed by ring-closing...Ch. 26 - 26.20 Draw the products formed in each...Ch. 26 - What organic halide is needed to convert lithium...Ch. 26 - 26.22 How can you convert ethynylcyclohexane to...Ch. 26 - 26.23 What compound is needed to convert styrene...Ch. 26 - 26.24 What steps are needed to convert to octane...Ch. 26 - Prob. 26.25PCh. 26 - Prob. 26.26PCh. 26 - 26.27 Draw the products (including stereoisomers)...Ch. 26 - 26.28 Treatment of cyclohexene with and forms...Ch. 26 - Prob. 26.29PCh. 26 - 26.30 What starting material is needed to prepare...Ch. 26 - Prob. 26.31PCh. 26 - Prob. 26.32PCh. 26 - When certain cycloalkenes are used in metathesis...Ch. 26 - 26.34 Draw the products formed in each reaction.
...Ch. 26 - Prob. 26.35PCh. 26 - Draw a stepwise mechanism for the following...Ch. 26 - Sulfur ylides, like the phosphorus ylides of...Ch. 26 - Although diazomethane is often not a useful...Ch. 26 - Prob. 26.39PCh. 26 - Prob. 26.40PCh. 26 - Prob. 26.41PCh. 26 - Prob. 26.42PCh. 26 - 26.43 Devise a synthesis of each compound using a...Ch. 26 - 26.44 Devise a synthesis of each compound from...Ch. 26 - 26.45 Devise a synthesis of each compound from...Ch. 26 - 26.46 Devise a synthesis of each substituted...Ch. 26 - Biaryls, compounds containing two aromatic rings...Ch. 26 - Prob. 26.48PCh. 26 - 26.49 Draw the product formed from the...Ch. 26 - Prob. 26.50PCh. 26 - 26.51 Devise a synthesis of each of the following...Ch. 26 - Prob. 26.52PCh. 26 - 26.53 The following conversion, carried out in the...Ch. 26 - Prob. 26.54PCh. 26 - 26.55 Dimethyl cyclopropanes can be prepared by...Ch. 26 - Prob. 26.56P
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- Devise a synthesis of each compound from benzene and organic alcohols containing four or fewer carbons. You may also use any required organic or inorganic reagents.arrow_forwardDevise a synthesis of each compound from benzene. You may also use any organic compounds having four carbons or fewer, and any required inorganic reagents. Co,CH3 a. b.arrow_forwardDevise a synthesis of each compound from ethanol (CH3CH2OH) as the only source of carbon atoms. You may use any other organic or inorganic reagents you choose.arrow_forward
- Devisa a synthesis of each compound from the indicated starting material. you may also use any organic compounds with one or two carbons and any needed inorganic reagents.arrow_forwardDevise a synthesis of each compound from CH3CH2OH as the only organic starting material; that is, every carbon in the product must come from a molecule of ethanol. You may use any other needed inorganic reagents.arrow_forwardDevise a synthesis of each compound from the indicated starting material. You may also use any organic compounds with one or two carbons and any needed inorganic reagents.arrow_forward
- Devise a synthesis of each compound using 1-bromobutane (CH3CH2CH2CH2Br) as the only organic starting material. You may use any other inorganic reagents.arrow_forwardDevise a synthesis of each compound using CH3CH3 as the only sourceof carbon atoms. You may use any other required organic or inorganicreagents.arrow_forwardDevise a synthesis of each compound from the indicated starting material. a. SO3H b. O₂N ن OH Br OHarrow_forward
- Synthesize each compound from cyclohexanol, ethanol, and any other needed reagents.arrow_forward8. Devise a synthesis of each compound from the indicated starting material. CI OH OH Br a. b. C. SO;H CH3 O,N ČH3arrow_forwardDevise a synthesis of each compound from phenol (C6H5OH) and any other organic or inorganic reagents.arrow_forward
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