Concept explainers
(a)
Interpretation: Product of the given coupling reaction is to be predicted.
Concept introduction: Organocuprate reagents
Answer to Problem 26.1P
The product of the given coupling reaction is octane as shown below.
Explanation of Solution
Species containing copper-carbon bonds are known as organocuprate reagents. These reagents act as nucleophille and react with organic halides to form coupling products that contains new
Figure 1
Product formed from the coupling reaction is shown in Figure 1.
(b)
Interpretation: Product of the coupling reaction is to be predicted.
Concept introduction: Organocuprate reagents
Only one alkyl groupof the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.
Answer to Problem 26.1P
The product of the coupling reaction is
Explanation of Solution
Species containing copper-carbon bonds are known as organocuprate reagents. These reagents act as nucleophille and react with organic halides to form coupling products that contains new
Figure 2
Product formed from the coupling reaction is shown in Figure 2.
(c)
Interpretation: Product of the coupling reaction is to be predicted.
Concept introduction: Organocuprate reagents
Only one alkyl groupof the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.
Answer to Problem 26.1P
The product of the coupling reaction is
Explanation of Solution
Species containing copper-carbon bonds are known as organocuprate reagents. These reagents acting as nucleophille and react with organic halides to form coupling products that contains new
Figure 3
Product formed from the coupling reaction is shown in Figure 3.
(d)
Interpretation: Product of the coupling reaction is to be predicted.
Concept introduction: Organocuprate reagents
Only one alkyl groupof the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.
Answer to Problem 26.1P
The product of the coupling reaction is
Explanation of Solution
Species containing copper-carbon bonds are known as organocuprate reagents. These reagents act as nucleophille and react with organic halides to form coupling products that contains new
Figure 4
Product formed from the coupling reaction is shown in Figure 4.
Want to see more full solutions like this?
Chapter 26 Solutions
Organic Chemistry-Package(Custom)
- (12) Which one of the following statements about fluo- rometry is FALSE? a) Fluorescence is better detected at 90 from the exci- tation direction. b) Fluorescence is typically shifted to longer wave- length from the excitation wavelength. c) For most fluorescent compounds, radiation is pro- duced by a transitionarrow_forwardDon't used Ai solutionarrow_forwardDon't used Ai solutionarrow_forward
- Don't used Ai solutionarrow_forwardIndicate the correct option.a) Graphite conducts electricity, being an isotropic materialb) Graphite is not a conductor of electricityc) Both are falsearrow_forward(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):arrow_forward
- 1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):arrow_forward(c) SOCI Best Lewis Structure 2 e group arrangement: shape/molecular geometry:_ (d) PCls Best Lewis Structure polarity: e group geometry:_ shape/molecular geometry:_ (e) Ba(BrO2): Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):arrow_forwardDon't used Ai solutionarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning