GENERAL,ORGANIC+BIOCHEM (LOOSELEAF)
10th Edition
ISBN: 9781264035090
Author: Denniston
Publisher: MCG
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Chapter 2.6, Problem 2.13Q
(a)
Interpretation Introduction
Interpretation:
The charge of the most probable ion from potassium and its isoelectronic element has to be provided.
(b)
Interpretation Introduction
Interpretation:
The charge of the most probable ion from Strontium and its isoelectronic element has to be provided.
(c)
Interpretation Introduction
Interpretation:
The charge of the most probable ion from Sulfur and its isoelectronic element has to be provided.
(d)
Interpretation Introduction
Interpretation:
The charge of the most probable ion from Magnesium and its isoelectronic element has to be provided.
(e)
Interpretation Introduction
Interpretation:
The charge of the most probable ion from Phosphorous and its isoelectronic element has to be provided.
(f)
Interpretation Introduction
Interpretation:
The charge of the most probable ion from Beryllium and its isoelectronic element has to be provided.
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 2 Solutions
GENERAL,ORGANIC+BIOCHEM (LOOSELEAF)
Ch. 2.1 - Calculate the number of protons, neutrons, and...Ch. 2.1 - How many protons, neutrons, and electrons are...Ch. 2.1 - How many protons, neutrons, and electrons are...Ch. 2.1 - The element nitrogen has two naturally occurring...Ch. 2.1 - Prob. 2.3PPCh. 2.3 - Prob. 2.3QCh. 2.3 - Prob. 2.4QCh. 2.4 - Prob. 2.5QCh. 2.4 - Using the periodic table, write the symbol for...Ch. 2.4 - Refer to the periodic table, and find the...
Ch. 2.4 - Refer to the periodic table, and find the...Ch. 2.4 - Prob. 2.9QCh. 2.4 - For each of the following element symbols, give...Ch. 2.5 - Prob. 2.4PPCh. 2.5 - Prob. 2.5PPCh. 2.5 - Prob. 2.6PPCh. 2.6 - Prob. 2.7PPCh. 2.6 - Prob. 2.8PPCh. 2.6 - Determine the number of protons and electrons in...Ch. 2.6 - Prob. 2.12QCh. 2.6 - Provide the charge of the most probable ion...Ch. 2.6 - Prob. 2.13QCh. 2.6 - Which of the following pairs of atoms and ions are...Ch. 2.6 - Prob. 2.10PPCh. 2.6 - Prob. 2.15QCh. 2.6 - Prob. 2.16QCh. 2.7 - Prob. 2.17QCh. 2.7 - Prob. 2.18QCh. 2 - Prob. 2.19QPCh. 2 - Why is the number of electrons not part of the...Ch. 2 - Fill in the blanks:
Isotopes of an element differ...Ch. 2 - Identify which of the following isotopic symbols...Ch. 2 - Identify the major difference and the major...Ch. 2 - Label each of the following statements as true or...Ch. 2 - Label each of the following statements as true or...Ch. 2 - The nuclei of three different atoms are depicted...Ch. 2 - Calculate the number of protons, neutrons, and...Ch. 2 - Calculate the number of protons, neutrons, and...Ch. 2 - An atom has nine protons, ten neutrons, and nine...Ch. 2 - An atom has nineteen protons, twenty neutrons, and...Ch. 2 - How many protons are in the nucleus of the isotope...Ch. 2 - Prob. 2.32QPCh. 2 - Selenium-80 is a naturally occurring isotope used...Ch. 2 - Prob. 2.34QPCh. 2 - Write symbols for each isotope:
Each atom contains...Ch. 2 - Prob. 2.36QPCh. 2 - The element copper has two naturally occurring...Ch. 2 - The element lithium has two naturally occurring...Ch. 2 - Prob. 2.39QPCh. 2 - Prob. 2.40QPCh. 2 - Describe the experiment that provided the basis...Ch. 2 - Prob. 2.42QPCh. 2 - Prob. 2.43QPCh. 2 - Prob. 2.44QPCh. 2 - Prob. 2.45QPCh. 2 - Prob. 2.46QPCh. 2 - Prob. 2.47QPCh. 2 - Prob. 2.48QPCh. 2 - Prob. 2.49QPCh. 2 - Prob. 2.50QPCh. 2 - Prob. 2.51QPCh. 2 - Prob. 2.52QPCh. 2 - Describe electromagnetic radiation according to...Ch. 2 - Prob. 2.54QPCh. 2 - Is the following statement true or false?
Light of...Ch. 2 - Prob. 2.56QPCh. 2 - Prob. 2.57QPCh. 2 - Prob. 2.58QPCh. 2 - Describe the process that occurs when electrical...Ch. 2 - When electrical energy is applied to an element in...Ch. 2 - Prob. 2.61QPCh. 2 - Prob. 2.62QPCh. 2 - Prob. 2.63QPCh. 2 - Prob. 2.64QPCh. 2 - What was the major contribution of Bohr’s atomic...Ch. 2 - What was the major deficiency of Bohr’s atomic...Ch. 2 - Provide the atomic number, atomic mass, and name...Ch. 2 - Provide the atomic number, atomic mass, and name...Ch. 2 - Prob. 2.69QPCh. 2 - Prob. 2.70QPCh. 2 - Which group of the periodic table is known as the...Ch. 2 - Prob. 2.72QPCh. 2 - For each of the elements Na, Ni, Al, P, Cl, and...Ch. 2 - Prob. 2.74QPCh. 2 - Prob. 2.75QPCh. 2 - Prob. 2.76QPCh. 2 - Distinguish between a principal energy level and a...Ch. 2 - Distinguish between a sublevel and an orbital.
Ch. 2 - Sketch a diagram and describe our current model of...Ch. 2 - How is a 2s orbital different from a 1s orbital?
Ch. 2 - Prob. 2.81QPCh. 2 - For any given principal energy level, what is the...Ch. 2 - State the Pauli exclusion principle. Explain how...Ch. 2 - State Hund’s rule. Determine whether the following...Ch. 2 - Using the periodic table, write the electron...Ch. 2 - Using the periodic table, write the electron...Ch. 2 - Using the periodic table, write the electron...Ch. 2 - Using the periodic table, write the electron...Ch. 2 - Which of the following electron configurations are...Ch. 2 - Prob. 2.90QPCh. 2 - Determine whether the following orbital diagrams...Ch. 2 - Identify the element for each of the orbital...Ch. 2 - Use the periodic table and determine the shorthand...Ch. 2 - Prob. 2.94QPCh. 2 - Prob. 2.95QPCh. 2 - Prob. 2.96QPCh. 2 - State the octet rule.
Ch. 2 - Prob. 2.98QPCh. 2 - Prob. 2.99QPCh. 2 - Prob. 2.100QPCh. 2 - How many total electrons and valence electrons are...Ch. 2 - Prob. 2.102QPCh. 2 - Prob. 2.103QPCh. 2 - Prob. 2.104QPCh. 2 - Prob. 2.105QPCh. 2 - Predict the number of valence electrons in an atom...Ch. 2 - Prob. 2.107QPCh. 2 - Prob. 2.108QPCh. 2 - Prob. 2.109QPCh. 2 - Prob. 2.110QPCh. 2 - Prob. 2.111QPCh. 2 - Prob. 2.112QPCh. 2 - Prob. 2.113QPCh. 2 - Prob. 2.114QPCh. 2 - Prob. 2.115QPCh. 2 - Prob. 2.116QPCh. 2 - Prob. 2.117QPCh. 2 - Prob. 2.118QPCh. 2 - Prob. 2.119QPCh. 2 - Prob. 2.120QPCh. 2 - Prob. 2.121QPCh. 2 - Prob. 2.122QPCh. 2 - Prob. 2.123QPCh. 2 - Prob. 2.124QPCh. 2 - Explain why a positive ion is always smaller than...Ch. 2 - Prob. 2.126QPCh. 2 - Prob. 2.127QPCh. 2 - Prob. 2.128QPCh. 2 - For the isotope chlorine-37:
How many protons are...Ch. 2 - A natural sample of chromium, taken from the...Ch. 2 - For the element sulfur, provide the following...Ch. 2 - Prob. 5MCPCh. 2 - Prob. 7MCP
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