CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
8th Edition
ISBN: 2818440043505
Author: Bruice
Publisher: PEARSON
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Chapter 25.8, Problem 21P

The fluoro-substitued geranyl pyrophosphate shown here reacts with isopentenyl pyrophosphate to form fluoro-substitued farnesyl pyrophosphate. The rate of the reaction is less than 1% of the rate of the reaction when unsubstiuted geranyl pyrophosphate is used. What does this tell you about the mechanism of the reaction?

Chapter 25.8, Problem 21P, The fluoro-substitued geranyl pyrophosphate shown here reacts with isopentenyl pyrophosphate to form

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1
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CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY

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