ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
6th Edition
ISBN: 9781266633973
Author: SMITH
Publisher: MCG
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Chapter 25.4, Problem 13P
Interpretation Introduction

(a)

Interpretation: The product (including stereochemistry) formed from the given pair of reactants in a thermal [4+2] cycloaddition reaction is to be drawn.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to the product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile.

Interpretation Introduction

(b)

Interpretation: The product (including stereochemistry) formed from the given pair of reactants in a thermal [4+2] cycloaddition reaction is to be drawn.

Concept introduction: A chemical reaction that involves [4+2] cycloaddition is called Diels-Alder reaction. The reactant molecules that give rise to product are diene and dienophile. The rate of reaction is fast when the electronegative group is attached to dienophile.

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29. Use frontier orbital analysis (HOMO-LUMO interactions) to decide whether the following dimerization is 1) thermally allowed or forbidden and 2) photochemically allowed or forbidden. +
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