ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
4th Edition
ISBN: 9781119659556
Author: Klein
Publisher: WILEY
Question
Book Icon
Chapter 25.3, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  1

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  3

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  5

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  6

(d)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  7

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  8

Blurred answer
Students have asked these similar questions
7 Draw the starting alkyl bromide that would produce this alkyne under these conditions. F Drawing 1. NaNH2, A 2. H3O+ £ 4 Temps to rise Tomorrow Q Search H2
7 Comment on the general features of the predicted (extremely simplified) ¹H- NMR spectrum of lycopene that is provided below. 00 6 57 PPM 3 2 1 0
Indicate the compound formula: dimethyl iodide (propyl) sulfonium.

Chapter 25 Solutions

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS

Knowledge Booster
Background pattern image
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY