ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
4th Edition
ISBN: 9781119659556
Author: Klein
Publisher: WILEY
Question
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Chapter 25.3, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  1

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  3

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  5

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  6

(d)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  7

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS, Chapter 25.3, Problem 13CC , additional homework tip  8

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Students have asked these similar questions
From the given compound, choose the proton that best fits each given description. a CH2 CH 2 Cl b с CH2 F Most shielded: (Choose one) Least shielded: (Choose one) Highest chemical shift: (Choose one) Lowest chemical shift: (Choose one) ×
Consider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 1H NMR spectrum? Note: A multiplet is considered one signal.
For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither. Compound m/z of M* peak m/z of M + 2 peak ratio of M+ : M + 2 peak Which element is present? A 122 no M + 2 peak not applicable (Choose one) B 78 80 3:1 (Choose one) C 227 229 1:1 (Choose one)

Chapter 25 Solutions

ORGANIC CHEMISTRY (LL)-W/WILEYPLUS

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