Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide
Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide
3rd Edition
ISBN: 9781119351610
Author: David Klein
Publisher: Wiley Plus
Question
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Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide, Chapter 25.3, Problem 12CC , additional homework tip  1

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide, Chapter 25.3, Problem 12CC , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide, Chapter 25.3, Problem 12CC , additional homework tip  3

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide, Chapter 25.3, Problem 12CC , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide, Chapter 25.3, Problem 12CC , additional homework tip  5

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide, Chapter 25.3, Problem 12CC , additional homework tip  6

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Chapter 25 Solutions

Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide

Ch. 25.2 - Prob. 10CCCh. 25.3 - Prob. 11CCCh. 25.3 - Prob. 12CCCh. 25.3 - Prob. 13CCCh. 25.3 - Prob. 2LTSCh. 25.3 - Prob. 14PTSCh. 25.3 - Prob. 15ATSCh. 25.3 - Prob. 16ATSCh. 25.3 - Prob. 17CCCh. 25.3 - Prob. 18CCCh. 25.3 - Prob. 19CCCh. 25.3 - Prob. 20CCCh. 25.4 - Prob. 3LTSCh. 25.4 - Prob. 21PTSCh. 25.4 - Prob. 22ATSCh. 25.4 - Prob. 23ATSCh. 25.4 - Prob. 24ATSCh. 25.4 - Prob. 25CCCh. 25.4 - Prob. 26CCCh. 25.4 - Prob. 27CCCh. 25.4 - Prob. 28CCCh. 25.4 - Prob. 29CCCh. 25.5 - Prob. 30CCCh. 25.5 - Prob. 4LTSCh. 25.5 - Prob. 31PTSCh. 25.5 - Prob. 32ATSCh. 25.5 - Prob. 33ATSCh. 25.6 - Prob. 5LTSCh. 25.6 - Prob. 34PTSCh. 25.6 - Prob. 35ATSCh. 25.6 - Prob. 36ATSCh. 25.6 - Prob. 6LTSCh. 25.6 - Prob. 37PTSCh. 25.6 - Prob. 38ATSCh. 25.7 - Prob. 39CCCh. 25 - Prob. 40PPCh. 25 - Prob. 41PPCh. 25 - Prob. 42PPCh. 25 - Prob. 43PPCh. 25 - Prob. 44PPCh. 25 - Prob. 45PPCh. 25 - Prob. 46PPCh. 25 - Prob. 47PPCh. 25 - Prob. 48PPCh. 25 - Prob. 49PPCh. 25 - Prob. 50PPCh. 25 - Prob. 51PPCh. 25 - Prob. 52PPCh. 25 - Prob. 53PPCh. 25 - Prob. 54PPCh. 25 - Prob. 55PPCh. 25 - Prob. 56PPCh. 25 - Prob. 57PPCh. 25 - Prob. 58PPCh. 25 - Prob. 59PPCh. 25 - Prob. 60PPCh. 25 - Prob. 61PPCh. 25 - Prob. 62PPCh. 25 - Prob. 63PPCh. 25 - Prob. 64PPCh. 25 - Prob. 65PPCh. 25 - Prob. 66PPCh. 25 - Prob. 67PPCh. 25 - Prob. 68PPCh. 25 - Prob. 69PPCh. 25 - Prob. 70PPCh. 25 - Prob. 71PPCh. 25 - Prob. 72PPCh. 25 - Prob. 73PPCh. 25 - Prob. 74PPCh. 25 - Prob. 75PPCh. 25 - Prob. 76PPCh. 25 - Prob. 77PPCh. 25 - Prob. 78PPCh. 25 - Prob. 79PPCh. 25 - Prob. 80PPCh. 25 - Prob. 81PPCh. 25 - Prob. 82PPCh. 25 - Prob. 83PPCh. 25 - Prob. 84IPCh. 25 - Prob. 85IPCh. 25 - Prob. 86IPCh. 25 - Prob. 87IPCh. 25 - Prob. 88IPCh. 25 - Prob. 89IPCh. 25 - Prob. 90CPCh. 25 - We saw in Section 25.6 that DCC can be used to...Ch. 25 - Prob. 92CP
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