(a)
Interpretation:
The amino acids required for obtaining the given aldehyde and the compound responsible for purple coloration need to be identified.
Concept introduction:
Ninhydrin react with primary
To draw : To identify the amino acids required to form the given
(b)
Interpretation:
The amino acids required for obtaining the given aldehyde and the compound responsible for purple coloration need to be identified.
Concept introduction:
Ninhydrin react with primary amines to give a purple colored product. This is a qualitative and quantitative test. The aldehyde is obtained as by-product. The general scheme can be shown as,
To draw : To identify the structure of compound responsible for purple color.
(c)
Interpretation:
The amino acids required for obtaining the given aldehyde and the compound responsible for purple coloration need to be identified.
Concept introduction:
Ninhydrin react with primary amines to give a purple colored product. This is a qualitative and quantitative test. The aldehyde is obtained as by-product. The purple coloration is seen due to compound that has more conjugated systems. The more conjugation is present in the system the more colored the compound will be. The general scheme can be shown as,
To draw : To identify the origin of the purple color.
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Chapter 25 Solutions
ORGANIC CHEMISTRY 1 TERM ACCESS
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
- What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.arrow_forwardQuestion 6 What is the major product of the following Diels-Alder reaction? ? Aldy by day of A. H о B. C. D. E. OB OD Oc OE OAarrow_forwardNonearrow_forward
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