EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321830555
Author: KARTY
Publisher: VST
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Question
Chapter 25, Problem 25.70P
Interpretation Introduction
Interpretation:
An initial step propagation steps and two plausible termination steps by a chain- reaction mechanism is to be proposed.
Concept introduction:
A free radical chain reaction involves free radicals in a cyclic sequence of steps, called propagation steps, which are responsible for converting overall reactants into overall products. An initiation step is responsible for producing the free radical that enters the propagation cycle. A termination step removes free radicals from the propagation cycle and is responsible for slowing the overall reaction.
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יווי
10
20
30
40
50
60
70
3.5
3
2.5
2
1.5
1
[ppm]
3.5
3
2.5
2
1.5
1
6 [ppm]
1
1.5
-2.5
3.5
2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
Question
Which of the following predicts the theoretical yield of SO2(g) from the reaction?
Responses
1.2 g
Answer A: 1.2 grams
A
41 g
Answer B: 41 grams
B
77 g
Answer C: 77 grams
C
154 g
Answer D: 154 grams
D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Chapter 25 Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
Ch. 25 - Prob. 25.1PCh. 25 - Prob. 25.2PCh. 25 - Prob. 25.3PCh. 25 - Prob. 25.4PCh. 25 - Prob. 25.5PCh. 25 - Prob. 25.6PCh. 25 - Prob. 25.7PCh. 25 - Prob. 25.8PCh. 25 - Prob. 25.9PCh. 25 - Prob. 25.10P
Ch. 25 - Prob. 25.11PCh. 25 - Prob. 25.12PCh. 25 - Prob. 25.13PCh. 25 - Prob. 25.14PCh. 25 - Prob. 25.15PCh. 25 - Prob. 25.16PCh. 25 - Prob. 25.17PCh. 25 - Prob. 25.18PCh. 25 - Prob. 25.19PCh. 25 - Prob. 25.20PCh. 25 - Prob. 25.21PCh. 25 - Prob. 25.22PCh. 25 - Prob. 25.23PCh. 25 - Prob. 25.24PCh. 25 - Prob. 25.25PCh. 25 - Prob. 25.26PCh. 25 - Prob. 25.27PCh. 25 - Prob. 25.28PCh. 25 - Prob. 25.29PCh. 25 - Prob. 25.30PCh. 25 - Prob. 25.31PCh. 25 - Prob. 25.32PCh. 25 - Prob. 25.33PCh. 25 - Prob. 25.34PCh. 25 - Prob. 25.35PCh. 25 - Prob. 25.36PCh. 25 - Prob. 25.37PCh. 25 - Prob. 25.38PCh. 25 - Prob. 25.39PCh. 25 - Prob. 25.40PCh. 25 - Prob. 25.41PCh. 25 - Prob. 25.42PCh. 25 - Prob. 25.43PCh. 25 - Prob. 25.44PCh. 25 - Prob. 25.45PCh. 25 - Prob. 25.46PCh. 25 - Prob. 25.47PCh. 25 - Prob. 25.48PCh. 25 - Prob. 25.49PCh. 25 - Prob. 25.50PCh. 25 - Prob. 25.51PCh. 25 - Prob. 25.52PCh. 25 - Prob. 25.53PCh. 25 - Prob. 25.54PCh. 25 - Prob. 25.55PCh. 25 - Prob. 25.56PCh. 25 - Prob. 25.57PCh. 25 - Prob. 25.58PCh. 25 - Prob. 25.59PCh. 25 - Prob. 25.60PCh. 25 - Prob. 25.61PCh. 25 - Prob. 25.62PCh. 25 - Prob. 25.63PCh. 25 - Prob. 25.64PCh. 25 - Prob. 25.65PCh. 25 - Prob. 25.66PCh. 25 - Prob. 25.67PCh. 25 - Prob. 25.68PCh. 25 - Prob. 25.69PCh. 25 - Prob. 25.70PCh. 25 - Prob. 25.71PCh. 25 - Prob. 25.72PCh. 25 - Prob. 25.73PCh. 25 - Prob. 25.74PCh. 25 - Prob. 25.75PCh. 25 - Prob. 25.76PCh. 25 - Prob. 25.77PCh. 25 - Prob. 25.1YTCh. 25 - Prob. 25.2YTCh. 25 - Prob. 25.3YTCh. 25 - Prob. 25.4YTCh. 25 - Prob. 25.5YTCh. 25 - Prob. 25.6YTCh. 25 - Prob. 25.7YTCh. 25 - Prob. 25.8YTCh. 25 - Prob. 25.9YTCh. 25 - Prob. 25.10YTCh. 25 - Prob. 25.11YTCh. 25 - Prob. 25.12YTCh. 25 - Prob. 25.13YTCh. 25 - Prob. 25.14YTCh. 25 - Prob. 25.15YTCh. 25 - Prob. 25.16YTCh. 25 - Prob. 25.17YTCh. 25 - Prob. 25.18YTCh. 25 - Prob. 25.19YTCh. 25 - Prob. 25.20YTCh. 25 - Prob. 25.21YTCh. 25 - Prob. 25.22YTCh. 25 - Prob. 25.23YTCh. 25 - Prob. 25.24YT
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