The structure for vasopressin is to be proposed. Concept introduction: Vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient. It comprises 9 amino acids. Amino acids are carbon containing compounds that possess two functional groups named as amine ( − NH 2 ) and carboxyl ( − COOH ) and these are prepared by reductive amination of α − ketoacids by using transaminase enzyme and bromination of carboxylic acid groups followed by amination. Reductive amination comprises transformation of carbonyl group of keto acids to an imine intermediate, which leads to the formation of an amine. Transaminase enzymes are specifically used for speed up the transamination reactions.

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Answer 1

Question

Chapter 24.9E, Problem 24.23P

Interpretation Introduction

Interpretation:

The structure for vasopressin is to be proposed.

Concept introduction:

Vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient. It comprises 9 amino acids. Amino acids are carbon containing compounds that possess two functional groups named as amine (−NH2) and carboxyl (−COOH) and these are prepared by reductive amination of α−ketoacids by using transaminase enzyme and bromination of carboxylic acid groups followed by amination. Reductive amination comprises transformation of carbonyl group of keto acids to an imine intermediate, which leads to the formation of an amine. Transaminase enzymes are specifically used for speed up the transamination reactions.

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Answer 2

Question

Chapter 24.9E, Problem 24.23P

Interpretation Introduction

Interpretation:

The structure for vasopressin is to be proposed.

Concept introduction:

Vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient. It comprises 9 amino acids. Amino acids are carbon containing compounds that possess two functional groups named as amine (−NH2) and carboxyl (−COOH) and these are prepared by reductive amination of α−ketoacids by using transaminase enzyme and bromination of carboxylic acid groups followed by amination. Reductive amination comprises transformation of carbonyl group of keto acids to an imine intermediate, which leads to the formation of an amine. Transaminase enzymes are specifically used for speed up the transamination reactions.

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Answer 3

Question

Chapter 24.9E, Problem 24.23P

Interpretation Introduction

Interpretation:

The structure for vasopressin is to be proposed.

Concept introduction:

Vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient. It comprises 9 amino acids. Amino acids are carbon containing compounds that possess two functional groups named as amine (−NH2) and carboxyl (−COOH) and these are prepared by reductive amination of α−ketoacids by using transaminase enzyme and bromination of carboxylic acid groups followed by amination. Reductive amination comprises transformation of carbonyl group of keto acids to an imine intermediate, which leads to the formation of an amine. Transaminase enzymes are specifically used for speed up the transamination reactions.

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Answer 4

Question

Chapter 24.9E, Problem 24.23P

Interpretation Introduction

Interpretation:

The structure for vasopressin is to be proposed.

Concept introduction:

Vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient. It comprises 9 amino acids. Amino acids are carbon containing compounds that possess two functional groups named as amine (−NH2) and carboxyl (−COOH) and these are prepared by reductive amination of α−ketoacids by using transaminase enzyme and bromination of carboxylic acid groups followed by amination. Reductive amination comprises transformation of carbonyl group of keto acids to an imine intermediate, which leads to the formation of an amine. Transaminase enzymes are specifically used for speed up the transamination reactions.

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Answer 5

Chapter 24.9E, Problem 24.23P

Interpretation Introduction

Interpretation:

The structure for vasopressin is to be proposed.

Concept introduction:

Vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient. It comprises 9 amino acids. Amino acids are carbon containing compounds that possess two functional groups named as amine (−NH2) and carboxyl (−COOH) and these are prepared by reductive amination of α−ketoacids by using transaminase enzyme and bromination of carboxylic acid groups followed by amination. Reductive amination comprises transformation of carbonyl group of keto acids to an imine intermediate, which leads to the formation of an amine. Transaminase enzymes are specifically used for speed up the transamination reactions.

Answer 6

Chapter 24.9E, Problem 24.23P

Interpretation Introduction

Interpretation:

The structure for vasopressin is to be proposed.

Concept introduction:

Vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient. It comprises 9 amino acids. Amino acids are carbon containing compounds that possess two functional groups named as amine (−NH2) and carboxyl (−COOH) and these are prepared by reductive amination of α−ketoacids by using transaminase enzyme and bromination of carboxylic acid groups followed by amination. Reductive amination comprises transformation of carbonyl group of keto acids to an imine intermediate, which leads to the formation of an amine. Transaminase enzymes are specifically used for speed up the transamination reactions.

Answer 7

Chapter 24.9E, Problem 24.23P

Interpretation Introduction

Interpretation:

The structure for vasopressin is to be proposed.

Concept introduction:

Vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient. It comprises 9 amino acids. Amino acids are carbon containing compounds that possess two functional groups named as amine (−NH2) and carboxyl (−COOH) and these are prepared by reductive amination of α−ketoacids by using transaminase enzyme and bromination of carboxylic acid groups followed by amination. Reductive amination comprises transformation of carbonyl group of keto acids to an imine intermediate, which leads to the formation of an amine. Transaminase enzymes are specifically used for speed up the transamination reactions.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 24.2A - Draw three-dimensional representations of the...Ch. 24.2A - Prob. 24.2P Ch. 24.2B - The herbicide glyphosate (Roundup) kills plants by...Ch. 24.4 - Draw the structure of the predominant form of a....Ch. 24.4 - Draw the resonance forms of a protonated guanidino...Ch. 24.4 - Although tryptophan contains a heterocyclic amine,...Ch. 24.4 - Prob. 24.7P Ch. 24.4 - Prob. 24.8P Ch. 24.5A - Show how the following amino acids might be formed...Ch. 24.5B - Prob. 24.10P

Solution Summary: The author explains that vasopressin is a peptide prohormone that regulates the effective osmotic pressure gradient.

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Chapter 24 Solutions