The more stable chair conformation for the given compounds are needed to be drawn. Concept introduction: Haworth projection is used to represent sugars in their cyclic forms. In Haworth projection, α-indicates the –OH group of anomeric carbon C1 and CH 2 OH substituent on the C5 carbon is trans to each other. D indicates the CH 2 OH substituent on the C5 carbon is on up position. The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively. Chair conformation is drawn according to the respective carbons in Haworth projection. Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial , the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position. To draw: the more stable chair conformation form for the given compound (a).

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Answer 1

Question

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS). Ca, ppm V, ppm SCa, arb. units SV, arb. units 20.0 10.0 14375.11 14261.02 40.0 10.0 36182.15 17997.10 60.0 10.0 39275.74 12988.01 80.0 10.0 57530.75 14268.54 100.0…

A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C. H₂O(g) + C₁₂O(g) = 2 HOCl(g) K = 0.0900 at 25°C с Calculate the equilibrium concentrations of each gas at 25 °C. [H₂O]= [C₁₂O]= [HOCI]= M Σ M

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Answer 2

Question

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Expert Solution & Answer

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Answer 3

Question

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Answer 6

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

Answer 7

Chapter 24.5, Problem 16PTS

(a)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation form for the given compound (a).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (b).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The more stable chair conformation for the given compounds are needed to be drawn.

Concept introduction:

Haworth projection is used to represent sugars in their cyclic forms.

In Haworth projection,

α-indicates the –OH group of anomeric carbon C1 and CH2OH substituent on the C5 carbon is trans to each other.

D indicates the CH2OH substituent on the C5 carbon is on up position.

The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

Chair conformation is drawn according to the respective carbons in Haworth projection.

Stability of chair conformation is depending upon the positions of bulky substituents whether on axial or equatorial, the location of bulky substituents on equatorial position is more stable than bulky substituents on axial position.

To draw: the more stable chair conformation for the given compound (c).

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 24.2 - Prob. 1CC Ch. 24.2 - Prob. 2CC Ch. 24.2 - Prob. 3CC Ch. 24.2 - Prob. 4CC Ch. 24.2 - Prob. 5CC Ch. 24.2 - Prob. 6CC Ch. 24.4 - Prob. 7CC Ch. 24.4 - Prob. 8CC Ch. 24.5 - Prob. 1LTS Ch. 24.5 - Prob. 9PTS

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Chapter 24 Solutions