EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
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Chapter 24.5, Problem 12PTS

(a)

Interpretation Introduction

Interpretation:

The Haworth projection for each of the given compounds are needed to be drawn.

Concept introduction:

  • Haworth projection is used to represent sugars in their cyclic forms.
  • In Haworth projection,
    • α-indicates the –OH group of anomeric carbon C1 and -CH2OH substituent on the C5 carbon is trans to each other.
    • D indicates the -CH2OH substituent on the C5 carbon is on up position.
    • The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

To draw: the Haworth projection for the given compound (a).

(b)

Interpretation Introduction

Interpretation:

The Haworth projection for each of the given compounds are needed to be drawn.

Concept introduction:

  • Haworth projection is used to represent sugars in their cyclic forms.
  • In Haworth projection,
    • α-indicates the –OH group of anomeric carbon C1 and -CH2OH substituent on the C5 carbon is trans to each other.
    • D indicates the -CH2OH substituent on the C5 carbon is on up position.
    • The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

To draw: the Haworth projection for the given compound (b).

(c)

Interpretation Introduction

Interpretation:

The Haworth projection for each of the given compounds are needed to be drawn.

Concept introduction:

  • Haworth projection is used to represent sugars in their cyclic forms.
  • In Haworth projection,
    • α-indicates the –OH group of anomeric carbon C1 and -CH2OH substituent on the C5 carbon is trans to each other.
    • D indicates the -CH2OH substituent on the C5 carbon is on up position.
    • The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

To draw: the Haworth projection for the given compound (c).

(d)

Interpretation Introduction

Interpretation:

The Haworth projection for each of the given compounds are needed to be drawn.

Concept introduction:

  • Haworth projection is used to represent sugars in their cyclic forms.
  • In Haworth projection,
    • α-indicates the –OH group of anomeric carbon C1 and -CH2OH substituent on the C5 carbon is trans to each other.
    • D indicates the -CH2OH substituent on the C5 carbon is on up position.
    • The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

To draw: the Haworth projection for the given compound (d).

 (e)

Interpretation Introduction

Interpretation:

The Haworth projection for each of the given compounds are needed to be drawn.

Concept introduction:

  • Haworth projection is used to represent sugars in their cyclic forms.
  • In Haworth projection,
    • α-indicates the –OH group of anomeric carbon C1 and -CH2OH substituent on the C5 carbon is trans to each other.
    • D indicates the -CH2OH substituent on the C5 carbon is on up position.
    • The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

To draw: the Haworth projection for the given compound (e).

(f)

Interpretation Introduction

Interpretation:

The Haworth projection for each of the given compounds are needed to be drawn.

Concept introduction:

  • Haworth projection is used to represent sugars in their cyclic forms.
  • In Haworth projection,
    • α-indicates the –OH group of anomeric carbon C1 and -CH2OH substituent on the C5 carbon is trans to each other.
    • D indicates the -CH2OH substituent on the C5 carbon is on up position.
    • The right side and left side –OH groups of chiral carbons in fisher projection are drawn as down side and upward side respectively.

To draw: the Haworth projection for the given compound (f).

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Chapter 24 Solutions

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG

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