ORGANIC CHEMISTRY WILEYPLUS ACCESS>I<
4th Edition
ISBN: 9781119850151
Author: Klein
Publisher: WILEY
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Draw the Fischer projection of D-fructose.
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Consider this step in a radical reaction:
Y
What type of step is this? Check all that apply.
Draw the products of the step on the right-hand side of the drawing area
below. If more than one set of products is possible, draw any set.
Also, draw the mechanism arrows on the left-hand side of the drawing
area to show how this happens.
ionization
propagation
initialization
passivation
none of the above
22.16 The following groups are ortho-para directors.
(a)
-C=CH₂
H
(d)
-Br
(b)
-NH2
(c)
-OCHS
Draw a contributing structure for the resonance-stabilized cation formed during elec-
trophilic aromatic substitution that shows the role of each group in stabilizing the
intermediate by further delocalizing its positive charge.
22.17 Predict the major product or products from treatment of each compound with
Cl₁/FeCl₂-
OH
(b)
NO2
CHO
22.18 How do you account for the fact that phenyl acetate is less reactive toward electro-
philic aromatic substitution than anisole?
Phenyl acetate
Anisole
CH
(d)
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- Is an acid-base reaction the only type of reaction that would cause leavening products to rise?arrow_forwardHelp me understand this! Thank you in advance.arrow_forward22.22 For each compound, indicate which group on the ring is more strongly activating and then draw a structural formula of the major product formed by nitration of the compound. Br CHO (a) CH3 (b) (c) CHO CH3 SO₂H (d) ☑ OCHS NO₂ (e) (f) CO₂H NHCOCH3 NHCOCH, (h) CHS 22.23 The following molecules each contain two aromatic rings. (b) 000-100- H3C (a) (c) Which ring in each undergoes electrophilic aromatic substitution more readily? Draw the major product formed on nitration.arrow_forward
- V Consider this step in a radical reaction: Br: ? What type of step is this? Check all that apply. Draw the products of the step on the right-hand side of the drawing area below. If more than one set of products is possible, draw any set. Also, draw the mechanism arrows on the left-hand side of the drawing area to show how this happens. ⚫ionization termination initialization neutralization none of the abc Explanation Check 80 Ο F3 F1 F2 2 F4 01 % do5 $ 94 #3 X 5 C MacBook Air 25 F5 F6 66 ©2025 ˇ F7 29 & 7 8arrow_forwardShow how to convert ethyl benzene to (a) 2,5-dichlorobenzoic acid and (b) 2,4-dichlorobenzoic acid.arrow_forwardno aiarrow_forward
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