GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780134193601
Author: Petrucci
Publisher: PEARSON
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Chapter 24, Problem 7E
Interpretation Introduction

(a)

Interpretation:

The structure of coordinate complex [FeBr( ox)2]2 needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(b)

Interpretation:

The structure of coordinate complex [CoBr4( NH 3 )2] needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(c)

Interpretation:

The structure of coordinate complex [Cu(EDTA)]2 needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(d)

Interpretation:

The structure of coordinate complex [CrBr2( H 2 O)4]+ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(e)

Interpretation:

The structure of coordinate complex [PtBr6]2 needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

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Consider the reactions 1. [Cr(H2O)6]** + [C©CI(NH3)s]* → [Co(NH3)s(H2O)]²* + [CrCl(H2O)s]** 2. [Fe(CN)6]* + [Mo(CN)s]-→ [Fe(CN)6]³¯ + [Mo(CN)8]* Which one of the following is the correct statement? (i) Both involve an inner sphere mechanism (ii) Both involve an outer sphere mechanism (iii) Reaction 1 follows inner sphere and reaction 2 follows outer sphere mechanism (iv) Reaction 1 follows outer sphere and reaction 2 follows inner sphere mechanism (A) i (B) ii (C) iv (D) ii
Why is [Fe(OH2)6]3+ prepared in an acidic solution? A. It is a Bronsted acid in aqueous solution B. It is stabilized against reduction in acid C. It is not soluble in water at pH = 7.0 D. All of the choices
1. Which would you expect to produce an aqueous solution with a lower pH? A 0.1 M solution of Cr(NO3)3, Mo(NO3)2, Fe(NOs)2, or TIO2? Explain your reasoning.

Chapter 24 Solutions

GENERAL CHEMISTRY-MOD.MASTERINGCHEM.

Ch. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - If A, B, C, and D are four different ligands, a....Ch. 24 - Prob. 14ECh. 24 - Prob. 15ECh. 24 - The structures of four complex ions are given....Ch. 24 - Prob. 17ECh. 24 - Prob. 18ECh. 24 - Prob. 19ECh. 24 - In contrast to the case of Co2+ considered in...Ch. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Prob. 24ECh. 24 - Prob. 25ECh. 24 - Prob. 26ECh. 24 - Prob. 27ECh. 24 - Prob. 28ECh. 24 - Prob. 29ECh. 24 - Prob. 30ECh. 24 - Prob. 31ECh. 24 - Prob. 32ECh. 24 - Prob. 33ECh. 24 - Prob. 34ECh. 24 - Prob. 35ECh. 24 - Prob. 36ECh. 24 - Prob. 37ECh. 24 - Draw dashed and solid wedge diagrams of...Ch. 24 - Prob. 39IAECh. 24 - Prob. 40IAECh. 24 - Prob. 41IAECh. 24 - Prob. 42IAECh. 24 - Prob. 43IAECh. 24 - Prob. 44IAECh. 24 - Prob. 45IAECh. 24 - Prob. 46IAECh. 24 - Prob. 47IAECh. 24 - Prob. 48IAECh. 24 - Prob. 49IAECh. 24 - Prob. 50IAECh. 24 - Prob. 51IAECh. 24 - Prob. 52IAECh. 24 - Prob. 53IAECh. 24 - Prob. 54IAECh. 24 - The compound CoCl22H2O4NH2 may be one of the...Ch. 24 - Prob. 56IAECh. 24 - Provide a valence bond description of the bonding...Ch. 24 - Prob. 58IAECh. 24 - Prob. 59IAECh. 24 - Prob. 60IAECh. 24 - Prob. 61IAECh. 24 - Prob. 62IAECh. 24 - The graph that follows represents the molar...Ch. 24 - Prob. 64FPCh. 24 - Prob. 65FPCh. 24 - The crystal field stabilization energy (CFSE) can...Ch. 24 - In your own words, describe the following terms or...Ch. 24 - Briefly describe each of the following ideas,...Ch. 24 - Prob. 69SAECh. 24 - The oxidation state of Ni in the complex ion...Ch. 24 - Prob. 71SAECh. 24 - Prob. 72SAECh. 24 - Prob. 73SAECh. 24 - Prob. 74SAECh. 24 - Prob. 75SAECh. 24 - The most soluble of the following solids in...Ch. 24 - Prob. 77SAECh. 24 - Write appropriate formulas for the following...Ch. 24 - Prob. 79SAECh. 24 - Prob. 80SAECh. 24 - Prob. 81SAECh. 24 - Prob. 82SAECh. 24 - Prob. 83SAECh. 24 - Prob. 84SAE
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