CHM 101 VOL 1 2014 >IC<
17th Edition
ISBN: 9781269932905
Author: Pearson
Publisher: PEARSON C
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Chapter 24, Problem 75E
Interpretation Introduction
Interpretation: The species that correspond to larger dispersion forces in an aqueous solution, among purines and pyrimidines, is to be stated.
Concept introduction: The weakest intermolecular forces are the dispersion forces. These are referred to as the temporary attractive forces that exist when electrons in two neighboring atoms occupy positions that correspond to the formation of a temporary dipole by the atoms.
To determine: The larger dispersion forces in aqueous solution among purines and the pyrimidines. It is given that the purines are adenine and guanines which have two ring in their structure, whereas the pyrimidines are thymine and cytosine which consists of a single ring.
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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression:
AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T
A. Calculate the value of AS for the process.
B. Next, use the Gibbs-Helmholtz equation:
(a(AG/T))
ΔΗ
-
T2
to calculate the value of AH for the process.
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Chapter 24 Solutions
CHM 101 VOL 1 2014 >IC<
Ch. 24.2 - Prob. 24.1.1PECh. 24.2 - Prob. 24.1.2PECh. 24.2 - How many hydrogen atoms are in 2, 2-...Ch. 24.2 - Prob. 24.2.2PECh. 24.3 - Prob. 24.3.1PECh. 24.3 - Prob. 24.3.2PECh. 24.3 - Prob. 24.4.1PECh. 24.3 - Prob. 24.4.2PECh. 24.3 - Prob. 24.5.1PECh. 24.3 - Prob. 24.5.2PE
Ch. 24.4 - Prob. 24.6.1PECh. 24.4 - Prob. 24.6.2PECh. 24.7 - Prob. 24.7.1PECh. 24.7 - Practice Exercise 2 Name the dipeptide and give...Ch. 24.7 - How many chiral carbon atoms are there in the...Ch. 24.7 - Prob. 24.8.2PECh. 24 - Prob. 1DECh. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Prob. 3ECh. 24 - Prob. 4ECh. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10ECh. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - Prob. 13ECh. 24 - Prob. 14ECh. 24 - Prob. 15ECh. 24 - Prob. 16ECh. 24 - Prob. 17ECh. 24 - Prob. 18ECh. 24 - Prob. 19ECh. 24 - Prob. 20ECh. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Prob. 24ECh. 24 - Prob. 25ECh. 24 - Prob. 26ECh. 24 - Prob. 27ECh. 24 - Prob. 28ECh. 24 - Prob. 29ECh. 24 - Prob. 30ECh. 24 - Prob. 31ECh. 24 - Prob. 32ECh. 24 - Prob. 33ECh. 24 - Prob. 34ECh. 24 - Prob. 35ECh. 24 - Prob. 36ECh. 24 - Prob. 37ECh. 24 - Prob. 38ECh. 24 - Prob. 39ECh. 24 - Describe the intermediate that is thought to form...Ch. 24 - Prob. 41ECh. 24 - Prob. 42ECh. 24 - Prob. 43ECh. 24 - Prob. 44ECh. 24 - Prob. 45ECh. 24 - Prob. 46ECh. 24 - Prob. 47ECh. 24 - Prob. 48ECh. 24 - Prob. 49ECh. 24 - Prob. 50ECh. 24 - Prob. 51ECh. 24 - Prob. 52ECh. 24 - Prob. 53ECh. 24 - Prob. 54ECh. 24 - Prob. 55ECh. 24 - Prob. 56ECh. 24 - Prob. 57ECh. 24 - Prob. 58ECh. 24 - Prob. 59ECh. 24 - Prob. 60ECh. 24 - Prob. 61ECh. 24 - Prob. 62ECh. 24 - Prob. 63ECh. 24 - Prob. 64ECh. 24 - Prob. 65ECh. 24 - Prob. 66ECh. 24 - Prob. 67ECh. 24 - Prob. 68ECh. 24 - Prob. 69ECh. 24 - Prob. 70ECh. 24 - Prob. 71ECh. 24 - Prob. 72ECh. 24 - Prob. 73ECh. 24 - Prob. 74ECh. 24 - Prob. 75ECh. 24 - Prob. 76ECh. 24 - Prob. 77ECh. 24 - Prob. 78ECh. 24 - Prob. 79ECh. 24 - Prob. 80ECh. 24 - Prob. 81AECh. 24 - Prob. 82AECh. 24 - Prob. 83AECh. 24 - Prob. 84AECh. 24 - Prob. 85AECh. 24 - Prob. 86AECh. 24 - Prob. 87AECh. 24 - Prob. 88AECh. 24 - Prob. 89AECh. 24 - Prob. 90AECh. 24 - Prob. 91AECh. 24 - Prob. 92AECh. 24 - Prob. 93AECh. 24 - Prob. 94AECh. 24 - Prob. 95IECh. 24 - Prob. 96IECh. 24 - Prob. 97IECh. 24 - Prob. 98IECh. 24 - Prob. 99IECh. 24 - A typical amino acid with one amino group and one...Ch. 24 - Prob. 101IECh. 24 - Prob. 102IE
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