ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 24, Problem 46DSP
Interpretation Introduction

Interpretation:

The possible structures for (+)-mannose and (+)-glucose from the given pairs are to be chosen.

Concept introduction:

In chain extension reactions of aldoses, the carbon atom is added to the aldehyde group and forms sugars with one more carbon atom that the substrate.

Molecules containing two identical chiral centers can be achiral.

The stereo centers in the original sugar remain unaffected in chain extension reactions.

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