The structure of the major product of the given reaction is to be drawn. Concept introduction: IO 4 − reacts with a vicinal diol to form a periodate ester. The ester then undergoes a [ 4 + 2 ] cycloelimination, resulting in the cleavage of the C − C bond of the diol, producing two carbonyl groups. If an aldehyde is produced as a result of this oxidative cleavage, it is not oxidized further to a carboxyl group.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24, Problem 24.59P

Interpretation Introduction

Interpretation:

The structure of the major product of the given reaction is to be drawn.

Concept introduction:

IO4− reacts with a vicinal diol to form a periodate ester. The ester then undergoes a [4+2] cycloelimination, resulting in the cleavage of the C−C bond of the diol, producing two carbonyl groups. If an aldehyde is produced as a result of this oxidative cleavage, it is not oxidized further to a carboxyl group.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24, Problem 24.59P

Interpretation Introduction

Interpretation:

The structure of the major product of the given reaction is to be drawn.

Concept introduction:

IO4− reacts with a vicinal diol to form a periodate ester. The ester then undergoes a [4+2] cycloelimination, resulting in the cleavage of the C−C bond of the diol, producing two carbonyl groups. If an aldehyde is produced as a result of this oxidative cleavage, it is not oxidized further to a carboxyl group.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24, Problem 24.59P

Interpretation Introduction

Interpretation:

The structure of the major product of the given reaction is to be drawn.

Concept introduction:

IO4− reacts with a vicinal diol to form a periodate ester. The ester then undergoes a [4+2] cycloelimination, resulting in the cleavage of the C−C bond of the diol, producing two carbonyl groups. If an aldehyde is produced as a result of this oxidative cleavage, it is not oxidized further to a carboxyl group.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24, Problem 24.59P

Interpretation Introduction