The position of ammonia that might have been incorporated in the original peptide is to be explained. Concept introduction: Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

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Answer 1

Question

Chapter 24, Problem 24.39SP

(a)

Interpretation Introduction

Interpretation:

The position of ammonia that might have been incorporated in the original peptide is to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(b)

Interpretation Introduction

Interpretation:

The functional groups at the N terminus and at the C terminus are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(c)

Interpretation Introduction

Interpretation:

The given findings are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

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Draw the reaction mechanism to predict the product of the transformation below: N H ? H₂O

Answer 2

Question

Chapter 24, Problem 24.39SP

(a)

Interpretation Introduction

Interpretation:

The position of ammonia that might have been incorporated in the original peptide is to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(b)

Interpretation Introduction

Interpretation:

The functional groups at the N terminus and at the C terminus are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(c)

Interpretation Introduction

Interpretation:

The given findings are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

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Answer 3

Question

Chapter 24, Problem 24.39SP

(a)

Interpretation Introduction

Interpretation:

The position of ammonia that might have been incorporated in the original peptide is to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(b)

Interpretation Introduction

Interpretation:

The functional groups at the N terminus and at the C terminus are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(c)

Interpretation Introduction

Interpretation:

The given findings are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

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Answer 4

Question

Chapter 24, Problem 24.39SP

(a)

Interpretation Introduction

Interpretation:

The position of ammonia that might have been incorporated in the original peptide is to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(b)

Interpretation Introduction

Interpretation:

The functional groups at the N terminus and at the C terminus are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(c)

Interpretation Introduction

Interpretation:

The given findings are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

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Answer 5

Chapter 24, Problem 24.39SP

(a)

Interpretation Introduction

Interpretation:

The position of ammonia that might have been incorporated in the original peptide is to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(b)

Interpretation Introduction

Interpretation:

The functional groups at the N terminus and at the C terminus are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

(c)

Interpretation Introduction

Interpretation:

The given findings are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

Answer 6

Chapter 24, Problem 24.39SP

(a)

Interpretation Introduction

Interpretation:

The position of ammonia that might have been incorporated in the original peptide is to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

Answer 7

Chapter 24, Problem 24.39SP

(a)

Interpretation Introduction

Interpretation:

The position of ammonia that might have been incorporated in the original peptide is to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The functional groups at the N terminus and at the C terminus are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The functional groups at the N terminus and at the C terminus are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given findings are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given findings are to be explained.

Concept introduction:

Amides are formed when amines and acids are condensed. It is accompanied by the loss of water molecule. The C-N bond has restricted rotation because of the partial double bond character. The free amine group located at the end of a polypeptide refers to N-terminal and the end of an amino acid chain which is terminated by a free carboxy group refers to a C-terminus.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 24.2A - Draw three-dimensional representations of the...Ch. 24.2A - Prob. 24.2P Ch. 24.2B - The herbicide glyphosate (Roundup) kills plants by...Ch. 24.4 - Draw the structure of the predominant form of a....Ch. 24.4 - Draw the resonance forms of a protonated guanidino...Ch. 24.4 - Although tryptophan contains a heterocyclic amine,...Ch. 24.4 - Prob. 24.7P Ch. 24.4 - Prob. 24.8P Ch. 24.5A - Show how the following amino acids might be formed...Ch. 24.5B - Prob. 24.10P

Solution Summary: The author explains the position of ammonia that might have been incorporated in the original peptide.

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