Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material. Concept Introduction: Conversion of aromatic amines to phenol: Aromatic amines converted to arenediazonium salt by reacting with N a N O 2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Question

9. OA. Rank the expected boiling points of the compounds shown below from highest to lowest. Place your answer appropriately in the box. Only the answer in the box will be graded. (3) points) OH OH بر بد بدید 2 3

Answer 1

Question

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

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9. OA. Rank the expected boiling points of the compounds shown below from highest to lowest. Place your answer appropriately in the box. Only the answer in the box will be graded. (3) points) OH OH بر بد بدید 2 3

There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS). Ca, ppm V, ppm SCa, arb. units SV, arb. units 20.0 10.0 14375.11 14261.02 40.0 10.0 36182.15 17997.10 60.0 10.0 39275.74 12988.01 80.0 10.0 57530.75 14268.54 100.0…

A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C. H₂O(g) + C₁₂O(g) = 2 HOCl(g) K = 0.0900 at 25°C с Calculate the equilibrium concentrations of each gas at 25 °C. [H₂O]= [C₁₂O]= [HOCI]= M Σ M

Answer 2

Question

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

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Answer 3

Question

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

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Answer 4

Question

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

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Answer 5

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Answer 6

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Answer 7

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Answer 18

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Ch. 23.1 - Prob. 23.1P Ch. 23.2 - Prob. 23.2P Ch. 23.2 - Prob. 23.3P Ch. 23.2 - Prob. 23.4P Ch. 23.5 - Prob. 23.5P Ch. 23.5 - Prob. AQ Ch. 23.5 - What is the hybridization of the nitrogen in...Ch. 23.5 - Prob. CQ Ch. 23.5 - The pKas of the conjugate acids of aniline and...Ch. 23.5 - Prob. EQ

Chapter 23 Solutions