(a)
Interpretation:
Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.
Concept Introduction:
Conversion of
Aromatic amines converted to arenediazonium salt by reacting with
(b)
Interpretation:
Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.
Concept Introduction:
Reaction of a primary aromatic amine with sodium nitrite:
The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous
Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by
Hydrogenation:
Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.
(c)
Interpretation:
Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.
Concept Introduction:
Reaction of a primary aromatic amine with sodium nitrite:
The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous
Hydrogenation:
Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.
(d)
Interpretation:
Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.
Concept Introduction:
Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous
(e)
Interpretation:
Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.
Concept Introduction:
Conversion of aromatic amines to phenol:
Aromatic amines converted to arenediazonium salt by reacting with
Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous
(f)
Interpretation:
Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.
Concept Introduction:
Hydrogenation:
Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.
Reaction of a primary aromatic amine with sodium nitrite:
The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous
Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by

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Chapter 23 Solutions
OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition
- Calculate the pH and the pOH of each of the following solutions at 25 °C for which the substances ionize completely: (a) 0.000259 M HClO4arrow_forwardWhat is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?arrow_forwardDetermine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. NaN₃arrow_forward
- A. Draw the structure of each of the following alcohols. Then draw and name the product you would expect to produce by the oxidation of each. a. 4-Methyl-2-heptanol b. 3,4-Dimethyl-1-pentanol c. 4-Ethyl-2-heptanol d. 5,7-Dichloro-3-heptanolarrow_forwardWhat is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?arrow_forwardCan I please get help with this.arrow_forward
- Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. N₂H₅ClO₄arrow_forwardPlease help me with identifying these.arrow_forwardCan I please get help with this?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
