A plausible method for converting aniline into para-nitroaniline has to be found. Concept Introduction : Acetylation of an aromatic ring leads to the introduction of acetyl group in the functional group attached to the ring such as in amino group. This is achieved by using acetyl chloride. A mixture of nitric acid and sulfuric acid is called a nitrating mixture. It leads the aromatic ring for the introduction of nitro group. Deacetylation means the removal of acetyl group which is done by aqueous acidic or basic conditions. To find: Convert aniline into para-nitroaniline by a plausible method Do acetylation in aniline using acetyl chloride

Question

Want to see the full answer?

Answer 1

Question

Chapter 23.8, Problem 22CC

Interpretation Introduction

Interpretation: A plausible method for converting aniline into para-nitroaniline has to be found.

Concept Introduction:

Acetylation of an aromatic ring leads to the introduction of acetyl group in the functional group attached to the ring such as in amino group. This is achieved by using acetyl chloride. A mixture of nitric acid and sulfuric acid is called a nitrating mixture. It leads the aromatic ring for the introduction of nitro group. Deacetylation means the removal of acetyl group which is done by aqueous acidic or basic conditions.

To find: Convert aniline into para-nitroaniline by a plausible method

Do acetylation in aniline using acetyl chloride

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Arrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5) Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them. ▸ View Available Hint(s) Least acidity NH&F NaBr NaOH NH,Br NaCIO Reset Greatest acidity

1. Consider the following molecular-level diagrams of a titration. O-HA molecule -Aion °° о ° (a) о (b) (c) (d) a. Which diagram best illustrates the microscopic representation for the EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium. hydroxide? (e)

Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…