Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781305176461
Author: Kotz
Publisher: Cengage
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Chapter 23.5, Problem 1RC
Interpretation Introduction
Interpretation: It should be determined of the expected monomers from given Polyacrylic acid compound structure.
Concept Introduction:
Given;
The sodium salt of this
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 23 Solutions
Chemistry & Chemical Reactivity
Ch. 23.2 - (a) Draw the nine isomers having the formula...Ch. 23.2 - Prob. 2CYUCh. 23.2 - There are 17 possible alkene isomers with the...Ch. 23.2 - Prob. 4CYUCh. 23.2 - Aniline, C6H5NH2, is the common name for...Ch. 23.2 - What is the systematic name for this alkane? (a)...Ch. 23.2 - Prob. 2RCCh. 23.2 - Prob. 3RCCh. 23.2 - Prob. 4RCCh. 23.2 - 5. How many isomers are possible for C6H4(CH3)Cl,...
Ch. 23.3 - Draw the structure of 1-butanol and alcohols that...Ch. 23.3 - Prob. 1RCCh. 23.3 - Prob. 2RCCh. 23.3 - What is the hybridization of nitrogen in...Ch. 23.3 - Prob. 4RCCh. 23.4 - (a) Name each of the following compounds and its...Ch. 23.4 - Prob. 1RCCh. 23.4 - Prob. 2RCCh. 23.4 - Prob. 3RCCh. 23.4 - Prob. 4RCCh. 23.4 - Prob. 1QCh. 23.4 - Prob. 2QCh. 23.4 - Prob. 3QCh. 23.5 - Kevlar is a well-known polymer that is now used to...Ch. 23.5 - Prob. 1QCh. 23.5 - Prob. 2QCh. 23.5 - Prob. 3QCh. 23.5 - Prob. 1RCCh. 23.5 - What is the atom economy for the reaction of...Ch. 23.5 - Prob. 5QCh. 23.5 - If drinking from a polycarbonate bottle, does a 15...Ch. 23.5 - Assume you weigh 156 lb. How much BPA do you...Ch. 23.5 - Prob. 8QCh. 23 - Prob. 1PSCh. 23 - What is the molecular formula for an alkane with...Ch. 23 - Prob. 3PSCh. 23 - Prob. 4PSCh. 23 - One of the structural isomers with the formula...Ch. 23 - Prob. 6PSCh. 23 - Prob. 7PSCh. 23 - Give the systematic name for the following alkane....Ch. 23 - Draw the structure of each of the following...Ch. 23 - Draw structures for the following compounds. (a)...Ch. 23 - Prob. 11PSCh. 23 - Prob. 12PSCh. 23 - Draw the structure of the chair form of...Ch. 23 - Prob. 14PSCh. 23 - Prob. 15PSCh. 23 - Prob. 16PSCh. 23 - Prob. 17PSCh. 23 - Prob. 18PSCh. 23 - Prob. 19PSCh. 23 - What structural requirement is necessary for an...Ch. 23 - A hydrocarbon with the formula C5H10, can be...Ch. 23 - Prob. 22PSCh. 23 - Prob. 23PSCh. 23 - Prob. 24PSCh. 23 - The compound 2-bromobutane is a product of...Ch. 23 - The compound 2,3-dibromo-2-methylhexane is formed...Ch. 23 - Prob. 27PSCh. 23 - Prob. 28PSCh. 23 - Prob. 29PSCh. 23 - Prob. 30PSCh. 23 - Prob. 31PSCh. 23 - Give the systematic name for each of the following...Ch. 23 - Prob. 33PSCh. 23 - Write an equation for the preparation of...Ch. 23 - Prob. 35PSCh. 23 - Prob. 36PSCh. 23 - Prob. 37PSCh. 23 - Prob. 38PSCh. 23 - Prob. 39PSCh. 23 - Name the following amines: (a) CH3CH2CH2NH2 (b)...Ch. 23 - Draw structural formulas for the four possible...Ch. 23 - Prob. 42PSCh. 23 - Prob. 43PSCh. 23 - Prob. 44PSCh. 23 - Prob. 45PSCh. 23 - Prob. 46PSCh. 23 - Prob. 47PSCh. 23 - Prob. 48PSCh. 23 - Prob. 49PSCh. 23 - Prob. 50PSCh. 23 - Give the structural formula and systematic name...Ch. 23 - Prob. 52PSCh. 23 - Prob. 53PSCh. 23 - Prob. 54PSCh. 23 - Prob. 55PSCh. 23 - Prob. 56PSCh. 23 - Prob. 57PSCh. 23 - Prob. 58PSCh. 23 - Prob. 59PSCh. 23 - Prob. 60PSCh. 23 - Identify the functional groups in the following...Ch. 23 - Prob. 62PSCh. 23 - Prob. 63PSCh. 23 - Prob. 64PSCh. 23 - Prob. 65PSCh. 23 - Prob. 66PSCh. 23 - Prob. 67GQCh. 23 - Prob. 68GQCh. 23 - Prob. 69GQCh. 23 - Prob. 70GQCh. 23 - Prob. 71GQCh. 23 - Prob. 72GQCh. 23 - Prob. 73GQCh. 23 - Write equations for the following reactions,...Ch. 23 - Prob. 75GQCh. 23 - Prob. 76GQCh. 23 - Draw the structure of each of the following...Ch. 23 - Prob. 78GQCh. 23 - Prob. 79GQCh. 23 - Draw structural formulas for possible isomers with...Ch. 23 - Prob. 81GQCh. 23 - Prob. 82GQCh. 23 - Prob. 83GQCh. 23 - Prob. 84GQCh. 23 - Prob. 85GQCh. 23 - Prob. 86GQCh. 23 - Draw the structure of glyceryl trilaurate, a fat....Ch. 23 - Prob. 88GQCh. 23 - Prob. 89GQCh. 23 - Prob. 90GQCh. 23 - Prob. 91GQCh. 23 - There are three ethers with the formula C4H10O....Ch. 23 - Review the opening photograph about chocolate...Ch. 23 - Prob. 94GQCh. 23 - Prob. 95ILCh. 23 - Prob. 96ILCh. 23 - Prob. 97ILCh. 23 - Prob. 98ILCh. 23 - Prob. 99ILCh. 23 - Prob. 100ILCh. 23 - Prob. 101ILCh. 23 - Prob. 102ILCh. 23 - Prob. 103ILCh. 23 - Prob. 104ILCh. 23 - Prob. 105ILCh. 23 - Prob. 106ILCh. 23 - Prob. 107SCQCh. 23 - Prob. 108SCQCh. 23 - Prob. 109SCQCh. 23 - Prob. 110SCQCh. 23 - Prob. 111SCQCh. 23 - Prob. 112SCQCh. 23 - Prob. 113SCQ
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