Chemistry the Central Science 13th Edition Custom for Lamar University
13th Edition
ISBN: 9781269962667
Author: Theodore L. Brown, H. Eugene LeMay Jr., Bruce E. Bursten, Batherine J. Murphy, Patrick M. Woodward, Matthew W. Stoltzfus
Publisher: Pearson Learning Center
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Question
Chapter 23.4, Problem 23.4.1PE
(a)
Interpretation Introduction
To determine: The overall reaction from the given mechanism.
(b)
Interpretation Introduction
To determine: The intermediates in the mechanism.
(c)
Interpretation Introduction
To determine: The molecularity of each of the elementary reaction.
(d)
Interpretation Introduction
To determine: The rate determining step of the reaction.
(e)
Interpretation Introduction
To determine: The rate law predicted by the mechanism.
(f)
Interpretation Introduction
To determine: The effect on the rate of the reaction if
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
Unlimited attempts
Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
Don't used hand raiting
Chapter 23 Solutions
Chemistry the Central Science 13th Edition Custom for Lamar University
Ch. 23.2 - Prob. 23.1.1PECh. 23.2 - Prob. 23.1.2PECh. 23.2 - Prob. 23.2.1PECh. 23.2 - Prob. 23.2.2PECh. 23.4 - The following mechanism has been proposed for the...Ch. 23.4 - Prob. 23.3.2PECh. 23.4 - Prob. 23.4.1PECh. 23.4 - Platinum nanoparticles of diameter ~2 nm are...Ch. 23.4 - 14.114 One of the many remarkable enzymes in the...Ch. 23.4 - 14.115N Suppose that, in the absence of catalyst,...
Ch. 23.5 - Prob. 23.6.1PECh. 23.5 - Dinitrogen pentoxide (N2O5) decomposes in...Ch. 23.6 - The reaction between ethyl iodide and hydroxide...Ch. 23.6 - Prob. 23.7.2PECh. 23.6 - Prob. 23.8.1PECh. 23.6 - Prob. 23.8.2PECh. 23 - Prob. 1DECh. 23 - Practice Exercise 1
If 8.0 g of NH4HS(s)...Ch. 23 - Practice Exercise 1 For the reaction 4 NH3(g) + 5...Ch. 23 - Prob. 3ECh. 23 - Prob. 4ECh. 23 - Phosphorus trichloride gas and chlorine gas react...Ch. 23 - Prob. 6ECh. 23 - Prob. 7ECh. 23 - 15.70 True or false: When the temperature of an...Ch. 23 - Prob. 9ECh. 23 - Prob. 10ECh. 23 - Prob. 11ECh. 23 - Prob. 12ECh. 23 - Prob. 13ECh. 23 - Prob. 14ECh. 23 - Prob. 15ECh. 23 - Practice Exercise 2 For the reaction H2 (g) + I2...Ch. 23 - Prob. 17ECh. 23 - Prob. 18ECh. 23 - Prob. 19ECh. 23 - Practice Exercise 1
A mixture of gaseous sulfur...Ch. 23 - Prob. 21ECh. 23 - Prob. 22ECh. 23 - Practice Exercise 2
The gaseous compound BrCl...Ch. 23 - Prob. 24ECh. 23 - Practice Exercise 2 At 1000 k, the value of Kp for...Ch. 23 - Prob. 26ECh. 23 - Prob. 27ECh. 23 - Practice Exercise 1 For the equilibrium Br2(g) +...Ch. 23 - Prob. 29ECh. 23 - Prob. 30ECh. 23 - Prob. 31ECh. 23 - Prob. 32ECh. 23 - Prob. 33ECh. 23 - Prob. 34ECh. 23 - Prob. 35ECh. 23 - 15.6 Ethene (C2H4) reacts with healogens (X2) by...Ch. 23 - When lead(IV) oxide is heated above 300 O C, it...Ch. 23 - Prob. 38ECh. 23 - The reactin A2(g) + B(g) + A(g) + AB(g) has an...Ch. 23 - The following graph represents the yield of the...Ch. 23 - Suppose that the gas-phase reactions A B and B A...Ch. 23 - Prob. 42ECh. 23 - Prob. 43ECh. 23 - Prob. 44ECh. 23 - Prob. 45ECh. 23 - Prob. 46ECh. 23 - Prob. 47ECh. 23 - Prob. 48ECh. 23 - Prob. 49ECh. 23 - Prob. 50ECh. 23 - Prob. 51ECh. 23 - Prob. 52ECh. 23 - Prob. 53ECh. 23 - Prob. 54ECh. 23 - Prob. 55ECh. 23 - Prob. 56ECh. 23 - Prob. 57ECh. 23 - Prob. 58ECh. 23 - For each of the following metals, write the...Ch. 23 - Prob. 60ECh. 23 - Prob. 61ECh. 23 - Prob. 62ECh. 23 - Prob. 63ECh. 23 - Prob. 64ECh. 23 - Prob. 65AECh. 23 - Prob. 66AECh. 23 - Prob. 67AECh. 23 - Prob. 68AECh. 23 - Prob. 69AECh. 23 - Prob. 70AECh. 23 - Prob. 71AECh. 23 - Prob. 72AECh. 23 - Prob. 73AECh. 23 - Prob. 74AECh. 23 - Prob. 75AECh. 23 - Prob. 76AECh. 23 - Prob. 77AECh. 23 - Prob. 78AECh. 23 - Prob. 79AECh. 23 - Prob. 80AECh. 23 - Prob. 81AECh. 23 - Prob. 82AECh. 23 - Prob. 83AECh. 23 - Prob. 84AECh. 23 - Prob. 85AECh. 23 - Prob. 86AECh. 23 - Prob. 87AECh. 23 - Prob. 88AECh. 23 - Prob. 89AECh. 23 - Prob. 90IECh. 23 - Prob. 91IECh. 23 - Prob. 92IECh. 23 - Prob. 93IECh. 23 - Prob. 94IECh. 23 - Prob. 95IECh. 23 - Prob. 96IECh. 23 - Prob. 97IECh. 23 - Prob. 98IECh. 23 - Prob. 99IECh. 23 - Prob. 100IECh. 23 - Prob. 101IE
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