
Chemistry
13th Edition
ISBN: 9781260162370
Author: Chang
Publisher: MCG
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Chapter 23.3, Problem 3RCF
Interpretation Introduction
Interpretation:
The name of the given complex compound written by a student is correct or wrong has to be found.
Concept Introduction:
Systematic naming is the standard name given in a systematic way to a unique complex compound.
Systematic naming for the complex compound can be given based on the few important guidelines given below:
- 1. The name of the ligand is followed by the name of the central metal cation of a complex compound.
- 2. If there is more than one type of ligand, then their names are arranged in an alphabetical order.
- 3. When more than one same type of ligands are present, then the Greek prefixes such as di, tri, tetra, penta, and hexa are used to specify their count such as 1,2,3,4.5 and 6 respectively.
- 4. The oxidation number of the metal is represented in roman numerals immediately following the metal ion name.
- 5. If the net charge of the complex ion is -ve, the central metal name should end with the suffix word –ate. Whereas if the net charge of the complex ion is +ve, then the central metal name should end with the suffix word –um.
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Students have asked these similar questions
(28 pts.) 7. Propose a synthesis for each of the following transformations. You must include the
reagents and product(s) for each step to receive full credit. The number of steps is provided.
(OC 4)
4 steps
4 steps
OH
b.
LTS
Solid:
AT=Te-Ti
Trial 1
Trial 2
Trial 3
Average
ΔΗ
Mass water, g
24.096
23.976
23.975
Moles of solid, mol
0.01763
001767
0101781
Temp. change, °C
2.9°C
11700
2.0°C
Heat of reaction, J
-292.37J -170.473
-193.26J
AH, kJ/mole
16.58K 9.647 kJ 10.85 kr
16.58K59.64701
KJ
mol
12.35k
Minimum AS,
J/mol K
41.582
mol-k
Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn &
Show your calculations for:
AH in J and then in kJ/mole for Trial 1:
qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J
qsin =
qrxn =
292.35 292.37J
AH in J = 292.375 0.2923kJ
0.01763m01
=1.65×107
AH in kJ/mol =
=
16.58K
0.01763mol
mol
qrx
Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con
Kelvin.)
AS=AHIT
(1.65×10(9.64×103) + (1.0
Jimai
For the compound: C8H17NO2
Use the following information to come up with a plausible structure:
8
This compound has "carboxylic acid amide" and ether functional groups.
The peaks at 1.2ppm are two signals that are overlapping one another.
One of the two signals is a doublet that represents 6 hydrogens; the
other signal is a quartet that represents 3 hydrogens.
Chapter 23 Solutions
Chemistry
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