CHEMISTRY:ATOMS FIRST-2 YEAR CONNECT
2nd Edition
ISBN: 9781260592320
Author: Burdge
Publisher: MCG
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Chapter 23.3, Problem 23.4WE
Interpretation Introduction
Interpretation:
The resonance structure, electrons shifting, and position of the negative charges of the hydrogen phosphate ion (
Concept introduction:
Resonance: it is a process of delocalization electrons with in the molecule.
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What does the phrase 'fit for purpose' mean in relation to analytical chemistry? Please provide examples too.
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
×
NO2
○ donating
O donating
O withdrawing
O withdrawing
O electron-rich
electron-deficient
no inductive effects
O no resonance effects
O similar to benzene
E
[
CI
O donating
withdrawing
O no inductive effects
Explanation
Check
○ donating
withdrawing
no resonance effects
electron-rich
electron-deficient
O similar to benzene
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Understanding how substituents activate
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
HN
NH2
Check
X
(Choose one)
(Choose one)
(Choose one)
(Choose one)
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Chapter 23 Solutions
CHEMISTRY:ATOMS FIRST-2 YEAR CONNECT
Ch. 23.2 - Prob. 23.1WECh. 23.2 - Prob. 1PPACh. 23.2 - Prob. 1PPBCh. 23.2 - Prob. 1PPCCh. 23.2 - Prob. 23.2WECh. 23.2 - Give the systematic IUPAC name for each of the...Ch. 23.2 - Prob. 2PPBCh. 23.2 - Prob. 2PPCCh. 23.2 - Prob. 23.2.1SRCh. 23.2 - Prob. 23.2.2SR
Ch. 23.2 - Prob. 23.2.3SRCh. 23.2 - Prob. 23.2.4SRCh. 23.2 - Prob. 23.2.5SRCh. 23.2 - Prob. 23.2.6SRCh. 23.3 - Prob. 23.3WECh. 23.3 - Prob. 3PPACh. 23.3 - Prob. 3PPBCh. 23.3 - Prob. 3PPCCh. 23.3 - Prob. 23.4WECh. 23.3 - Prob. 4PPACh. 23.3 - Prob. 4PPBCh. 23.3 - Prob. 4PPCCh. 23.3 - Prob. 23.3.1SRCh. 23.3 - Prob. 23.3.2SRCh. 23.3 - Which of the following pairs of species are...Ch. 23.3 - Prob. 23.3.4SRCh. 23.5 - Prob. 23.5WECh. 23.5 - Prob. 5PPACh. 23.5 - Prob. 5PPBCh. 23.5 - Prob. 23.5.1SRCh. 23.5 - Prob. 23.5.2SRCh. 23 - Prob. 23.1QPCh. 23 - Prob. 23.2QPCh. 23 - Prob. 23.3QPCh. 23 - Prob. 23.4QPCh. 23 - Prob. 23.5QPCh. 23 - Prob. 23.6QPCh. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - Prob. 23.9QPCh. 23 - Name each of the following compounds.Ch. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - Prob. 23.16QPCh. 23 - Prob. 23.17QPCh. 23 - Prob. 23.18QPCh. 23 - Prob. 23.19QPCh. 23 - Prob. 23.20QPCh. 23 - Prob. 23.21QPCh. 23 - Prob. 23.22QPCh. 23 - Prob. 23.23QPCh. 23 - Prob. 23.24QPCh. 23 - Prob. 23.25QPCh. 23 - Prob. 23.26QPCh. 23 - Prob. 23.27QPCh. 23 - Prob. 23.28QPCh. 23 - Prob. 23.29QPCh. 23 - Prob. 23.30QPCh. 23 - Prob. 23.31QPCh. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Fill in the blanks in the given paragraph with the...Ch. 23 - Prob. 23.36QPCh. 23 - Draw all possible structural isomers for the...Ch. 23 - Prob. 23.38QPCh. 23 - Prob. 23.39QPCh. 23 - Prob. 23.40QPCh. 23 - Prob. 23.41QPCh. 23 - Prob. 23.42QPCh. 23 - Prob. 23.43QPCh. 23 - Prob. 23.44QPCh. 23 - Prob. 23.45QPCh. 23 - Prob. 23.46QPCh. 23 - Prob. 23.47QPCh. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Prob. 23.52QPCh. 23 - (a) Define carbocation. (b) Which of the following...Ch. 23 - Prob. 23.54QPCh. 23 - Prob. 23.55QPCh. 23 - Prob. 23.56QPCh. 23 - Prob. 23.57QPCh. 23 - Prob. 23.58QPCh. 23 - Prob. 23.59QPCh. 23 - Consider the following reactions of butanal. In...Ch. 23 - Prob. 23.61QPCh. 23 - Prob. 23.62QPCh. 23 - Prob. 23.63QPCh. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - Prob. 23.67QPCh. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - Prob. 23.72QPCh. 23 - Prob. 23.73QPCh. 23 - Prob. 23.74QPCh. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QPCh. 23 - Prob. 23.77QPCh. 23 - Prob. 23.78QPCh. 23 - Prob. 23.79QPCh. 23 - Prob. 23.80QPCh. 23 - Prob. 23.81QPCh. 23 - Prob. 23.82QPCh. 23 - Prob. 23.83QPCh. 23 - Prob. 23.84QPCh. 23 - Prob. 23.85QPCh. 23 - Prob. 23.86QPCh. 23 - Prob. 23.87QPCh. 23 - Prob. 23.88QPCh. 23 - Prob. 23.89QPCh. 23 - Prob. 23.90QPCh. 23 - Prob. 23.91QPCh. 23 - Prob. 23.92QPCh. 23 - Prob. 23.93QPCh. 23 - Prob. 23.94QPCh. 23 - Prob. 23.95QPCh. 23 - Prob. 23.96QPCh. 23 - Prob. 23.97QPCh. 23 - Prob. 23.98QPCh. 23 - Prob. 23.99QPCh. 23 - Prob. 23.100QPCh. 23 - Prob. 23.101QPCh. 23 - Prob. 23.102QPCh. 23 - Prob. 23.103QPCh. 23 - Prob. 23.104QPCh. 23 - Prob. 23.105QP
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- Identifying electron-donating and electron-withdrawing effects on benzene For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Inductive Effects Resonance Effects Overall Electron-Density Molecule CF3 O donating O donating O withdrawing O withdrawing O no inductive effects O no resonance effects electron-rich electron-deficient O similar to benzene CH3 O donating O withdrawing O no inductive effects O donating O withdrawing Ono resonance effects O electron-rich O electron-deficient O similar to benzene Explanation Check Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forward* Hint: Think back to Chem 1 solubility rules. Follow Up Questions for Part B 12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant for the forward reaction? Explain. (4 pts) a) Changing the concentration of a reactant or product. (2 pts) b) Changing the temperature of an exothermic reaction. (2 pts) ofarrow_forwardDraw TWO general chemical equation to prepare Symmetrical and non-Symmetrical ethers Draw 1 chemical reaction of an etherarrow_forward
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- Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. OCH 3 (Choose one) OH (Choose one) Br (Choose one) Explanation Check NO2 (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Aarrow_forwardFor each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects O donating O withdrawing O no inductive effects Resonance Effects Overall Electron-Density ○ donating ○ withdrawing O no resonance effects O electron-rich O electron-deficient O similar to benzene Cl O donating O withdrawing ○ donating ○ withdrawing O no inductive effects O no resonance effects O Explanation Check O electron-rich O electron-deficient similar to benzene X © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forwardIdentifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forward
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