EBK CHEMISTRY: ATOMS FIRST
EBK CHEMISTRY: ATOMS FIRST
3rd Edition
ISBN: 8220103675505
Author: Burdge
Publisher: YUZU
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Chapter 23.2, Problem 2PPB

(a)

Interpretation Introduction

Interpretation:

The structure of the organic compounds should be given.

Concept introduction:

Organic compounds are named systematically by using IUPAC rules.

Name of the organic compounds are given according to the number of carbon present in the molecule for example

A molecule having one carbon atom, the molecule name will start with meth etc.…

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  1

If any halogens are present in the molecule, the name of the halogens as follows.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  2

Naming the substituted alkane:

  1. (1) Name the parent alkane (long alkyl chain)
  2. (2) Number the carbon
  3. (3) Name and number the substituent

If the molecules have the multiple substituents, the compound named as di, tri, tetra, penta, ect.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  3

If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.

The given compound is an alcohol (OH) , the compound name end up with ol. The name of the compound is given according to the number of carbon atom.

Example is given below

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  4

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  5

The given compound is an acid ( COOH ), the compound name end up with oic. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  6

The amides are derivatives of acids and it is named as the ending of alkane with amide.

For example

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  7

If the molecule is ester,

Esters end with “ate”

Example

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  8

The given compound is an aldehyde ( CHO ), the compound name end up with al. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  9

The given compound is a ketone ( CO ), the compound name end up with one. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  10

The given compound is an amine ( NH2 ), the compound name end up with amine. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  11

(b)

Interpretation Introduction

Interpretation:

The structure of the organic compounds should be given.

Concept introduction:

Organic compounds are named systematically by using IUPAC rules.

Name of the organic compounds are given according to the number of carbon present in the molecule for example

A molecule having one carbon atom, the molecule name will start with meth etc.…

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  12

If any halogens are present in the molecule, the name of the halogens as follows.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  13

Naming the substituted alkane:

  1. (4) Name the parent alkane (long alkyl chain)
  2. (5) Number the carbon
  3. (6) Name and number the substituent

If the molecules have the multiple substituents, the compound named as di, tri, tetra, penta, ect.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  14

If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.

The given compound is an alcohol (OH) , the compound name end up with ol. The name of the compound is given according to the number of carbon atom.

Example is given below

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  15

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  16

The given compound is an acid ( COOH ), the compound name end up with oic. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  17

The amides are derivatives of acids and it is named as the ending of alkane with amide.

For example

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  18

If the molecule is ester,

Esters end with “ate”

Example

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  19

The given compound is an aldehyde ( CHO ), the compound name end up with al. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  20

The given compound is a ketone ( CO ), the compound name end up with one. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  21

The given compound is an amine ( NH2 ), the compound name end up with amine. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  22

(c)

Interpretation Introduction

Interpretation:

The structure of the organic compounds should be given.

Concept introduction:

Organic compounds are named systematically by using IUPAC rules.

Name of the organic compounds are given according to the number of carbon present in the molecule for example

A molecule having one carbon atom, the molecule name will start with meth etc.…

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  23

If any halogens are present in the molecule, the name of the halogens as follows.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  24

Naming the substituted alkane:

  1. (7) Name the parent alkane (long alkyl chain)
  2. (8) Number the carbon
  3. (9) Name and number the substituent

If the molecules have the multiple substituents, the compound named as di, tri, tetra, penta, ect.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  25

If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.

The given compound is an alcohol (OH) , the compound name end up with ol. The name of the compound is given according to the number of carbon atom.

Example is given below

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  26

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  27

The given compound is an acid ( COOH ), the compound name end up with oic. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  28

The amides are derivatives of acids and it is named as the ending of alkane with amide.

For example

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  29

If the molecule is ester,

Esters end with “ate”

Example

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  30

The given compound is an aldehyde ( CHO ), the compound name end up with al. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  31

The given compound is a ketone ( CO ), the compound name end up with one. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  32

The given compound is an amine ( NH2 ), the compound name end up with amine. The name of the compound is given according to the number of carbon atom.

EBK CHEMISTRY: ATOMS FIRST, Chapter 23.2, Problem 2PPB , additional homework tip  33

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Draw a Lewis structure for each of the following molecules and assign charges where appropriate. The order in which the atoms are connected is given in parentheses. a. CIFCIF b. BrCNBrCN 0 c. SOCI2 × (CISCIO) SOC₁₂ (CISCI) You can draw both an octet and a valence shell expanded structure. Considering the following structural information, which is the better one: The measured S-OS-O bond length in SOC12SOCl2 is 1.43 Å. For comparison, that in SO2SO2 is 1.43 Å [Exercise 1-9, part (b)], that in CHзSOHCH3 SOH d. CH3NH2CH3NH2 (methanesulfenic acid) is 1.66 A. e. CH3OCH3 CH3 OCH3 NH2 f. N2H2× (HNNH) N2 H2 (HNNH) g. CH2COCH₂ CO h. HN3× (HNNN) HN3 (HNNN) i. N20 × (NNO) N2O (NNO)
bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]
PROBLEM 4 Solved Show how 1-butanol can be converted into the following compounds: a. PROBLEM 5+ b. d. -C= N

Chapter 23 Solutions

EBK CHEMISTRY: ATOMS FIRST

Ch. 23.2 - Prob. 23.2.3SRCh. 23.2 - Prob. 23.2.4SRCh. 23.2 - Prob. 23.2.5SRCh. 23.2 - Prob. 23.2.6SRCh. 23.3 - Prob. 23.3WECh. 23.3 - Prob. 3PPACh. 23.3 - Prob. 3PPBCh. 23.3 - Prob. 3PPCCh. 23.3 - Prob. 23.4WECh. 23.3 - Prob. 4PPACh. 23.3 - Prob. 4PPBCh. 23.3 - Prob. 4PPCCh. 23.3 - Prob. 23.3.1SRCh. 23.3 - Prob. 23.3.2SRCh. 23.3 - Which of the following pairs of species are...Ch. 23.3 - Prob. 23.3.4SRCh. 23.5 - Prob. 23.5WECh. 23.5 - Prob. 5PPBCh. 23.5 - Prob. 5PPCCh. 23.5 - Prob. 23.5.1SRCh. 23.5 - Prob. 23.5.2SRCh. 23 - Prob. 23.1QPCh. 23 - Prob. 23.2QPCh. 23 - Prob. 23.3QPCh. 23 - Prob. 23.4QPCh. 23 - Prob. 23.5QPCh. 23 - Prob. 23.6QPCh. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - Prob. 23.9QPCh. 23 - Name each of the following compounds.Ch. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - Prob. 23.16QPCh. 23 - Prob. 23.17QPCh. 23 - Prob. 23.18QPCh. 23 - Prob. 23.19QPCh. 23 - Prob. 23.20QPCh. 23 - Prob. 23.21QPCh. 23 - Prob. 23.22QPCh. 23 - Prob. 23.23QPCh. 23 - Prob. 23.24QPCh. 23 - Prob. 23.25QPCh. 23 - Prob. 23.26QPCh. 23 - Prob. 23.27QPCh. 23 - Prob. 23.28QPCh. 23 - Prob. 23.29QPCh. 23 - Prob. 23.30QPCh. 23 - Prob. 23.31QPCh. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Fill in the blanks in the given paragraph with the...Ch. 23 - Prob. 23.36QPCh. 23 - Draw all possible structural isomers for the...Ch. 23 - Prob. 23.38QPCh. 23 - Prob. 23.39QPCh. 23 - Prob. 23.40QPCh. 23 - Prob. 23.41QPCh. 23 - Prob. 23.42QPCh. 23 - Prob. 23.43QPCh. 23 - Prob. 23.44QPCh. 23 - Prob. 23.45QPCh. 23 - Prob. 23.46QPCh. 23 - Prob. 23.47QPCh. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Prob. 23.52QPCh. 23 - (a) Define carbocation. (b) Which of the following...Ch. 23 - Prob. 23.54QPCh. 23 - Prob. 23.55QPCh. 23 - Prob. 23.56QPCh. 23 - Prob. 23.57QPCh. 23 - Prob. 23.58QPCh. 23 - Prob. 23.59QPCh. 23 - Consider the following reactions of butanal. In...Ch. 23 - Prob. 23.61QPCh. 23 - Prob. 23.62QPCh. 23 - Prob. 23.63QPCh. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - Prob. 23.67QPCh. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - Prob. 23.72QPCh. 23 - Prob. 23.73QPCh. 23 - Prob. 23.74QPCh. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QPCh. 23 - Prob. 23.77QPCh. 23 - Prob. 23.78QPCh. 23 - Prob. 23.79QPCh. 23 - Prob. 23.80QPCh. 23 - Prob. 23.81QPCh. 23 - Prob. 23.82QPCh. 23 - Prob. 23.83QPCh. 23 - Prob. 23.84QPCh. 23 - Prob. 23.85QPCh. 23 - Prob. 23.86QPCh. 23 - Prob. 23.87QPCh. 23 - Prob. 23.88QPCh. 23 - Prob. 23.89QPCh. 23 - Prob. 23.90QPCh. 23 - Prob. 23.91QPCh. 23 - Prob. 23.92QPCh. 23 - Prob. 23.93QPCh. 23 - Prob. 23.94QPCh. 23 - Prob. 23.95QPCh. 23 - Prob. 23.96QPCh. 23 - Prob. 23.97QPCh. 23 - Prob. 23.98QPCh. 23 - Prob. 23.99QPCh. 23 - Prob. 23.100QPCh. 23 - Prob. 23.101QPCh. 23 - Prob. 23.102QPCh. 23 - Prob. 23.103QPCh. 23 - Prob. 23.104QPCh. 23 - Prob. 23.105QP
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