a) Interpretation: The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified. Concept introduction: The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product. To identify: The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.11, Problem 19P

Interpretation Introduction

a)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product.

To identify:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

Interpretation Introduction

b)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acrolein is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor, acrolein, to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acroline.

Interpretation Introduction

c)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with an α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.11, Problem 19P

Interpretation Introduction

a)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product.

To identify:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

Interpretation Introduction

b)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acrolein is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor, acrolein, to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acroline.

Interpretation Introduction

c)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with an α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.11, Problem 19P

Interpretation Introduction

a)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product.

To identify:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

Interpretation Introduction

b)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acrolein is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor, acrolein, to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acroline.

Interpretation Introduction

c)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with an α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.11, Problem 19P

Interpretation Introduction

a)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product.

To identify:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

Interpretation Introduction

b)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acrolein is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor, acrolein, to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acroline.

Interpretation Introduction

c)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with an α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one.

Expert Solution & Answer

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Answer 5

Chapter 23.11, Problem 19P

Interpretation Introduction

a)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product.

To identify:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

Interpretation Introduction

b)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acrolein is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor, acrolein, to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acroline.

Interpretation Introduction

c)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with an α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one.

Answer 6

Chapter 23.11, Problem 19P

Interpretation Introduction

a)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product.

To identify:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

Answer 7

Chapter 23.11, Problem 19P

Interpretation Introduction

a)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, ethyl acrylate, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the product.

To identify:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated, ethyl acrylate, is hydrolyzed.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acrolein is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor, acrolein, to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acroline.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acrolein is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with α, β- unsaturated acceptor, acrolein, to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, acroline.

Answer 10

Interpretation Introduction

c)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with an α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one.

Answer 11

Interpretation Introduction

c)

Interpretation:

The product that will be produced when the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one, is to be identified.

Concept introduction:

The enamine obtained by reacting a ketone with cyclic amine reacts with an α, β- unsaturated acceptor to yield a substituted enamine as the intermediate which upon hydrolysis gives the products.

To identify:

The product that will be produced by the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with α, β- unsaturated acceptor, pent-3-ene-2-one.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 23.1 - Prob. 1P Ch. 23.1 - Prob. 2P Ch. 23.3 - Prob. 3P Ch. 23.3 - Prob. 4P Ch. 23.4 - Prob. 5P Ch. 23.4 - 1-Butanol is prepared commercially by a route that...Ch. 23.4 - Prob. 7P Ch. 23.5 - Prob. 8P Ch. 23.6 - Prob. 9P Ch. 23.6 - What product would you Expect to obtain from base...

Solution Summary: The author explains the hydrolysis of the enamine obtained by reacting cyclopentanone and pyrrolidone with the unsaturated acceptor, ethyl acrylate.

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Chapter 23 Solutions