CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
8th Edition
ISBN: 2818440043505
Author: Bruice
Publisher: PEARSON
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Chapter 23.1, Problem 2P
Interpretation Introduction

Interpretation:

The product of given reaction should be determined.

Concept introduction:

  • NAD+ and NADH are the coenzymes associated with catabolic reactions- biological reactions that break down complex bio molecules in order to provide the cell with energy.
  • Catabolic reactions are predominately oxidation reaction.
  • NAD+ is the most common oxidizing agent in cells.
  • NAD+ and NADPH are the coenzymes associated with Anabolic reactions- biological reactions involved in synthesizing complex bio molecules.
  • Anabolic reactions are predominantly reduction.
  • Catabolic reactions are predominately oxidation reaction.
  • NADPH is the most common reducing agent in cells.
  • FAD Catalyses oxidation reaction; it is reducing to FADH2.

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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1
AE>AE₁ (Y/N) AE=AE₁ (Y/N) AE
Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and gives compound A. ? NH2 Br Br Propose a structural formula for compound A. You do not have to explicitly draw H atoms. You do not have to consider stereochemistry. In cases where there is more than one answer, just draw one. R3N C14H19NO2 + 2 R3NH*Br A

Chapter 23 Solutions

CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY

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