(a) Interpretation: The equations for the dissolution and oxidation-reduction reactions should be written. Concept introduction: Silver have two stable oxidation states as +1 and +2. Silver has higher reduction potentials than H + . Silver is durable and resistant to corrosion. Silver is a group 11 metal and does not react with HCl. But Ag and Cu can react with concentrated sulfuric or nitric acid.

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Answer 1

Question

Chapter 23, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The equations for the dissolution and oxidation-reduction reactions should be written.

Concept introduction:

Silver have two stable oxidation states as +1 and +2. Silver has higher reduction potentials than H⁺. Silver is durable and resistant to corrosion. Silver is a group 11 metal and does not react with HCl. But Ag and Cu can react with concentrated sulfuric or nitric acid.

Interpretation Introduction

(b)

Interpretation:

It should be shown that the oxidation reduction reaction is indeed spontaneous

Concept introduction:

In an electrochemical cell, there are two electrodes that can be observed.

If oxidation takes place on an electrode, that electrode is called anode. The species in that electrode remove electrons and itself gets oxidized.

If reduction takes place on an electrode, that electrode is called cathode. The species in that electrode absorbs electrons and itself gets reduced.

The electrode potential of cell can be calculated as follows:

E0cell= E0cathode − E0anode

When E⁰_c_e_l_l is positive the forward reaction is spontaneous.

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Answer 2

Question

Chapter 23, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The equations for the dissolution and oxidation-reduction reactions should be written.

Concept introduction:

Silver have two stable oxidation states as +1 and +2. Silver has higher reduction potentials than H⁺. Silver is durable and resistant to corrosion. Silver is a group 11 metal and does not react with HCl. But Ag and Cu can react with concentrated sulfuric or nitric acid.

Interpretation Introduction

(b)

Interpretation:

It should be shown that the oxidation reduction reaction is indeed spontaneous

Concept introduction:

In an electrochemical cell, there are two electrodes that can be observed.

If oxidation takes place on an electrode, that electrode is called anode. The species in that electrode remove electrons and itself gets oxidized.

If reduction takes place on an electrode, that electrode is called cathode. The species in that electrode absorbs electrons and itself gets reduced.

The electrode potential of cell can be calculated as follows:

E0cell= E0cathode − E0anode

When E⁰_c_e_l_l is positive the forward reaction is spontaneous.

Expert Solution & Answer

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Answer 3

Question

Chapter 23, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The equations for the dissolution and oxidation-reduction reactions should be written.

Concept introduction:

Silver have two stable oxidation states as +1 and +2. Silver has higher reduction potentials than H⁺. Silver is durable and resistant to corrosion. Silver is a group 11 metal and does not react with HCl. But Ag and Cu can react with concentrated sulfuric or nitric acid.

Interpretation Introduction

(b)

Interpretation:

It should be shown that the oxidation reduction reaction is indeed spontaneous

Concept introduction:

In an electrochemical cell, there are two electrodes that can be observed.

If oxidation takes place on an electrode, that electrode is called anode. The species in that electrode remove electrons and itself gets oxidized.

If reduction takes place on an electrode, that electrode is called cathode. The species in that electrode absorbs electrons and itself gets reduced.

The electrode potential of cell can be calculated as follows:

E0cell= E0cathode − E0anode

When E⁰_c_e_l_l is positive the forward reaction is spontaneous.

Expert Solution & Answer

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Answer 4

Question

Chapter 23, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The equations for the dissolution and oxidation-reduction reactions should be written.

Concept introduction:

Silver have two stable oxidation states as +1 and +2. Silver has higher reduction potentials than H⁺. Silver is durable and resistant to corrosion. Silver is a group 11 metal and does not react with HCl. But Ag and Cu can react with concentrated sulfuric or nitric acid.

Interpretation Introduction

(b)

Interpretation:

It should be shown that the oxidation reduction reaction is indeed spontaneous

Concept introduction:

In an electrochemical cell, there are two electrodes that can be observed.

If oxidation takes place on an electrode, that electrode is called anode. The species in that electrode remove electrons and itself gets oxidized.

If reduction takes place on an electrode, that electrode is called cathode. The species in that electrode absorbs electrons and itself gets reduced.

The electrode potential of cell can be calculated as follows:

E0cell= E0cathode − E0anode

When E⁰_c_e_l_l is positive the forward reaction is spontaneous.

Expert Solution & Answer

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Answer 5

Chapter 23, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The equations for the dissolution and oxidation-reduction reactions should be written.

Concept introduction:

Silver have two stable oxidation states as +1 and +2. Silver has higher reduction potentials than H⁺. Silver is durable and resistant to corrosion. Silver is a group 11 metal and does not react with HCl. But Ag and Cu can react with concentrated sulfuric or nitric acid.

Interpretation Introduction

(b)

Interpretation:

It should be shown that the oxidation reduction reaction is indeed spontaneous

Concept introduction:

In an electrochemical cell, there are two electrodes that can be observed.

If oxidation takes place on an electrode, that electrode is called anode. The species in that electrode remove electrons and itself gets oxidized.

If reduction takes place on an electrode, that electrode is called cathode. The species in that electrode absorbs electrons and itself gets reduced.

The electrode potential of cell can be calculated as follows:

E0cell= E0cathode − E0anode

When E⁰_c_e_l_l is positive the forward reaction is spontaneous.

Answer 6

Chapter 23, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The equations for the dissolution and oxidation-reduction reactions should be written.

Concept introduction:

Silver have two stable oxidation states as +1 and +2. Silver has higher reduction potentials than H⁺. Silver is durable and resistant to corrosion. Silver is a group 11 metal and does not react with HCl. But Ag and Cu can react with concentrated sulfuric or nitric acid.

Answer 7

Chapter 23, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The equations for the dissolution and oxidation-reduction reactions should be written.

Concept introduction:

Silver have two stable oxidation states as +1 and +2. Silver has higher reduction potentials than H⁺. Silver is durable and resistant to corrosion. Silver is a group 11 metal and does not react with HCl. But Ag and Cu can react with concentrated sulfuric or nitric acid.

Answer 8

Interpretation Introduction

(b)

Interpretation:

It should be shown that the oxidation reduction reaction is indeed spontaneous

Concept introduction:

In an electrochemical cell, there are two electrodes that can be observed.

If oxidation takes place on an electrode, that electrode is called anode. The species in that electrode remove electrons and itself gets oxidized.

If reduction takes place on an electrode, that electrode is called cathode. The species in that electrode absorbs electrons and itself gets reduced.

The electrode potential of cell can be calculated as follows:

E0cell= E0cathode − E0anode

When E⁰_c_e_l_l is positive the forward reaction is spontaneous.

Answer 9

Interpretation Introduction

(b)

Interpretation:

It should be shown that the oxidation reduction reaction is indeed spontaneous

Concept introduction:

In an electrochemical cell, there are two electrodes that can be observed.

If oxidation takes place on an electrode, that electrode is called anode. The species in that electrode remove electrons and itself gets oxidized.

If reduction takes place on an electrode, that electrode is called cathode. The species in that electrode absorbs electrons and itself gets reduced.

The electrode potential of cell can be calculated as follows:

E0cell= E0cathode − E0anode

When E⁰_c_e_l_l is positive the forward reaction is spontaneous.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - By means of orbital diagrams, write electron...Ch. 23 - Arrange the following species according to the...Ch. 23 - Describe how the transition elements compare with...Ch. 23 - With only minor irregularities, the melting points...Ch. 23 - Why do the atomic radii vary so much for two...Ch. 23 - Prob. 6E Ch. 23 - Which of me first transition series elements...Ch. 23 - Why is the number of common oxidation states for...Ch. 23 - As a group, the lanthanides are more reactive...Ch. 23 - The maximum difference in standard reduction...

Solution Summary: The author explains that the equations for the dissolution and oxidation-reduction reactions should be written.

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Chapter 23 Solutions