ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
3rd Edition
ISBN: 9781119781448
Author: Klein
Publisher: WILEY
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Chapter 23, Problem 51PP
Interpretation Introduction

Interpretation:

The structures for compounds 1, 2 and 3 in the given reactions and also the reason why compound A give one product whereas compound B gives two products should be identified.

Concept Introduction:

Grubbs catalyst: This catalyst is used to achieve alkene metathesis. It contain transition metal namely Ru which is doubly bonded with carbon atom.

  ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<, Chapter 23, Problem 51PP , additional homework tip  1

Reaction of an alkene with Grubbs, the vinyl positions in given alkene is separated from each other and finally fragments are recombined. The reaction is as follows,

    ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<, Chapter 23, Problem 51PP , additional homework tip  2

Dienes in presence of dilute solution, alkene metathesis serve as method of ring formation.

  ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<, Chapter 23, Problem 51PP , additional homework tip  3

Alkene metathesis: It involves two stages first; the starting material in presence of catalyst forms two possible intermediates.  Next the intermediates react with the starting material and results to form product.

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Chapter 23 Solutions

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