ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
3rd Edition
ISBN: 9781119477617
Author: Klein
Publisher: WILEY
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Chapter 23, Problem 46PP
Interpretation Introduction

Interpretation:

The two step synthesis required to achieve the given transformation should be identified.

Concept Introduction:

Grubbs catalyst: This catalyst is used to achieve alkene metathesis. It contain transition metal namely Ru which is doubly bonded with carbon atom.

  ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 23, Problem 46PP , additional homework tip  1

Dienes in presence of dilute solution, alkene metathesis serve as method of ring formation.

  ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY, Chapter 23, Problem 46PP , additional homework tip  2

Simmons–Smith reaction: It involves reaction of alkenes with organozinc reagent namely ICH2ZnI which results in formation of three–membered ring in product. This is a concerted reaction in which the configuration of starting alkene is preserved.

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Chapter 23 Solutions

ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY

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