Organic Chemistry, 12e Study Guide/Student Solutions Manual
Organic Chemistry, 12e Study Guide/Student Solutions Manual
12th Edition
ISBN: 9781119077329
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 23, Problem 2PP
Interpretation Introduction

Interpretation:

The isoprene units in the given compounds are to be shown and each of them as per their isoprene units are to be classified.

Concept introduction:

Essential oils are mixtures of odoriferous compounds that are extracted from plants by heating or steam distillation. These essential oils have important chemical composition of hydrocarbons called terpenes and oxygen-containing compounds called terpenoids.

A single isoprene unit consists of 5-carbon atoms with double bonds, and its chemical formula is 2methyl1,3butadiene. The structural formulae of isoprene and its single isoprene unit is as follows:

Organic Chemistry, 12e Study Guide/Student Solutions Manual, Chapter 23, Problem 2PP

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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