ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
12th Edition
ISBN: 9781119664635
Author: Solomons
Publisher: WILEY
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Chapter 23, Problem 2LGP

The biosynthesis of fatty acids is accomplished two carbons at a time by an enzyme complex called fatty acid synthetase. The biochemical reactions involved in fatty acid synthesis are described in Special Topic G (WileyPLUS). Each of these biochemical reactions has a counter-part in synthetic reactions you have studied. Consider the biochemical reactions involved in adding each −- C H 2 C H 2 −- segment during fatty acid biosynthesis (those in Special Topic G that begin with acetyl-S-ACP and malonyl-S-ACP, and end with butyryl-S-ACP). Write laboratory synthetic reactions using reagents and conditions you have studied (not biosynthetic reactions) that would accomplish the same sequence of transformations (i.e., the condensation–decarboxylation, ketone reduction, dehydration, and alkene reduction steps).

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In a system with an anodic overpotential, the variation of ŋ as a function of the current density: 1. at low fields is linear 2. at higher fields, it follows Tafel's law Find the range of current densities for which the overpotential has the same value as when calculated for cases 1 and 2 (maximum relative difference of 5% with respect to the behavior for higher fields). To which overpotential range does this correspond? Data: 10 = 1.5 mA cm², T = 300°C, ẞ = 0.64, R = 8.314 J K 1 mol‍¹ and F = 96485 C mol-1.
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