General Chemistry
11th Edition
ISBN: 9781305859142
Author: Ebbing, Darrell D., Gammon, Steven D.
Publisher: Cengage Learning,
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Question
Chapter 23, Problem 23.86QP
Interpretation Introduction
Interpretation:
Cis and trans isomers of 3-methyl-3-hexene has to be drawn.
Concept Introduction:
Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For
To draw: cis-trans isomer for 3-methyl-3-hexene.
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What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Chapter 23 Solutions
General Chemistry
Ch. 23.2 - Prob. 23.1ECh. 23.2 - In the model shown here, C atoms are black and H...Ch. 23.2 - Prob. 23.2CCCh. 23.3 - Prob. 23.2ECh. 23.3 - Prob. 23.3ECh. 23.5 - Prob. 23.4ECh. 23.5 - Prob. 23.5ECh. 23.5 - Prob. 23.6ECh. 23.5 - Prob. 23.7ECh. 23.5 - Prob. 23.8E
Ch. 23.5 - Give the IUPAC name for each of the following...Ch. 23.5 - Prob. 23.10ECh. 23.5 - Prob. 23.3CCCh. 23.6 - Prob. 23.11ECh. 23.6 - Prob. 23.12ECh. 23.6 - Prob. 23.13ECh. 23 - Give the molecular formula of an alkane with 25...Ch. 23 - Prob. 23.2QPCh. 23 - Prob. 23.3QPCh. 23 - Prob. 23.4QPCh. 23 - Prob. 23.5QPCh. 23 - Prob. 23.6QPCh. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - What would you expect to be the major product when...Ch. 23 - Prob. 23.10QPCh. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - Prob. 23.16QPCh. 23 - Prob. 23.17QPCh. 23 - What is the correct IUPAC name for the following...Ch. 23 - Prob. 23.19QPCh. 23 - Prob. 23.20QPCh. 23 - Explain why you wouldnt expect to find a compound...Ch. 23 - Catalytic cracking is an industrial process used...Ch. 23 - Prob. 23.23QPCh. 23 - In the models shown here, C atoms are black and H...Ch. 23 - Prob. 23.25QPCh. 23 - Prob. 23.26QPCh. 23 - Prob. 23.27QPCh. 23 - Prob. 23.28QPCh. 23 - Prob. 23.29QPCh. 23 - Prob. 23.30QPCh. 23 - Complete and balance the following equations. Note...Ch. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Prob. 23.35QPCh. 23 - Complete the following equation, giving only the...Ch. 23 - Prob. 23.37QPCh. 23 - What is the IUPAC name of each of the following...Ch. 23 - Prob. 23.39QPCh. 23 - Write the condensed structural formula for each of...Ch. 23 - Give the IUPAC name of each of the following. a...Ch. 23 - For each of the following, write the IUPAC name. a...Ch. 23 - Prob. 23.43QPCh. 23 - Prob. 23.44QPCh. 23 - Prob. 23.45QPCh. 23 - Prob. 23.46QPCh. 23 - Give the IUPAC name of each of the following...Ch. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Circle and name the functional group in each...Ch. 23 - Prob. 23.53QPCh. 23 - Prob. 23.54QPCh. 23 - Prob. 23.55QPCh. 23 - Prob. 23.56QPCh. 23 - What is the common name of each of the following...Ch. 23 - Prob. 23.58QPCh. 23 - Prob. 23.59QPCh. 23 - Prob. 23.60QPCh. 23 - Prob. 23.61QPCh. 23 - Prob. 23.62QPCh. 23 - Give the IUPAC name of each of the following...Ch. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - Prob. 23.67QPCh. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - A compound with a fragrant odor reacts with dilute...Ch. 23 - Prob. 23.73QPCh. 23 - Prob. 23.74QPCh. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QPCh. 23 - Prob. 23.77QPCh. 23 - Prob. 23.78QPCh. 23 - Prob. 23.79QPCh. 23 - Prob. 23.80QPCh. 23 - Prob. 23.81QPCh. 23 - Prob. 23.82QPCh. 23 - Prob. 23.83QPCh. 23 - Prob. 23.84QPCh. 23 - Prob. 23.85QPCh. 23 - Prob. 23.86QPCh. 23 - Prob. 23.87QPCh. 23 - Prob. 23.88QP
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