
EBK CHEMISTRY
12th Edition
ISBN: 8220102797857
Author: Chang
Publisher: YUZU
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Chapter 23, Problem 23.7QP
Interpretation Introduction
Interpretation: The highest oxidation states for scandium to copper to be predicted.
Concept Introduction:
Shielding effect: The effective nuclear charge between the nucleus and outer valence shell electrons is shield by the partially or completely filled inner most-subshell.
Stability of the metals: The partially-filled and completely filled orbitals are highly stable than the incompletely filled orbitals.
Highest Oxidation states: The removal of maximum number of electrons from an element gives the highest oxidation state.
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Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
For the decomposition reaction of N2O5(g): 2 N2O5(g) · 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5
-> NO2 + NO3_(K1)
NO2 + NO3 →> N2O5 (k-1)
→
NO2 + NO3
→
NO2 + O2 + NO (K2)
NO + N2O5
→ NO2 + NO2 + NO2 (K3)
Give the expression for the acceptable rate.
(A).
d[N₂O]
dt
=
-1
2k,k₂[N205]
k₁+k₂
d[N₂O5]
(B).
dt
=-k₁[N₂O₂] + k₁[NO2][NO3] - k₂[NO2]³
(C).
d[N₂O]
dt
=-k₁[N₂O] + k₁[N205] - K3 [NO] [N205]
(D).
d[N2O5]
=-k₁[NO] - K3[NO] [N₂05]
dt
A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 20.0 mL of the base solution, what is the pH of the resulting solution?
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
Chapter 23 Solutions
EBK CHEMISTRY
Ch. 23.1 - Identify the following transition metal atoms and...Ch. 23.3 - What is the difference between these two...Ch. 23.3 - Write the oxidation numbers of the metals in the...Ch. 23.3 - Prob. 2PECh. 23.3 - Prob. 3PECh. 23.3 - Prob. 2RCCh. 23.4 - Prob. 1RCCh. 23.5 - Prob. 4PECh. 23.5 - Prob. 1RCCh. 23 - What distinguishes a transition metal from a...
Ch. 23 - Why is zinc not considered a transition metal?Ch. 23 - Explain why atomic radii decrease very gradually...Ch. 23 - Without referring to the text, write the...Ch. 23 - Write the electron configurations of the following...Ch. 23 - Why do transition metals have more oxidation...Ch. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - Define the following terms: coordination compound,...Ch. 23 - Describe the interaction between a donor atom and...Ch. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - What are the systematic names for the following...Ch. 23 - Prob. 23.17QPCh. 23 - Prob. 23.18QPCh. 23 - Define the following terms: stereoisomers,...Ch. 23 - Prob. 23.20QPCh. 23 - Prob. 23.21QPCh. 23 - Prob. 23.22QPCh. 23 - Prob. 23.23QPCh. 23 - Prob. 23.24QPCh. 23 - Draw structures of all the geometric and optical...Ch. 23 - Prob. 23.26QPCh. 23 - Briefly describe crystal field theory.Ch. 23 - Prob. 23.28QPCh. 23 - What is the origin of color in a coordination...Ch. 23 - Prob. 23.30QPCh. 23 - Prob. 23.31QPCh. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Prob. 23.35QPCh. 23 - The absorption maximum for the complex ion...Ch. 23 - Prob. 23.37QPCh. 23 - A solution made by dissolving 0.875 g of...Ch. 23 - Prob. 23.39QPCh. 23 - Prob. 23.40QPCh. 23 - Prob. 23.41QPCh. 23 - The [Fe(CN)6]3 complex is more labile than the...Ch. 23 - Aqueous copper(II) sulfate solution is blue in...Ch. 23 - When aqueous potassium cyanide is added to a...Ch. 23 - A concentrated aqueous copper(II) chloride...Ch. 23 - Prob. 23.46QPCh. 23 - As we read across the first-row transition metals...Ch. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Chemical analysis shows that hemoglobin contains...Ch. 23 - Explain the following facts: (a) Copper and iron...Ch. 23 - A student in 1895 prepared three coordination...Ch. 23 - Prob. 23.55QPCh. 23 - From the standard reduction potentials listed in...Ch. 23 - Using the standard reduction potentials listed in...Ch. 23 - The Co2+-porphyrin complex is more stable than the...Ch. 23 - Prob. 23.59QPCh. 23 - Prob. 23.60QPCh. 23 - Hydrated Mn2+ ions are practically colorless (see...Ch. 23 - Which of the following hydrated cations are...Ch. 23 - Prob. 23.63QPCh. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - The compound 1,1,1-trifluoroacetylacetone (tfa) is...Ch. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - Commercial silver-plating operations frequently...Ch. 23 - Draw qualitative diagrams for the crystal field...Ch. 23 - (a) The free Cu(I) ion is unstable in solution and...Ch. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QP
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Similar questions
- For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forwardR lactam or lactone considering as weak acid or weak base and whyarrow_forward81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium uliaarrow_forward
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