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Concept explainers
(a)
Interpretation:
The formula for the given name of the complex compound has to be written.
Concept Introduction:
Systematic naming is the standard name given in a systematic way to a unique complex compound.
Systematic naming for the complex compound can be given based on the few important guidelines given below:
- 1. The name of the ligand is followed by the name of the central metal cation of a complex compound.
- 2. If there is more than one type of ligand, then their names are arranged in an alphabetical order.
- 3. More than one ligand of the same type have to be numbered using the Greek prefixes such as di, tri, tetra, penta, and hexa which represent the count of 1,2,3,4.5 and 6 respectively.
- 4. The roman numerals immediately following the metal ion name is the oxidation number of the metal
- 5. If the net charge of the complex ion is -ve, the central metal name should end with the suffix word –ate. Whereas if the net charge of the complex ion is +ve, then the central metal name should end with the suffix word –um.
(b)
Interpretation:
The formula for the given name of the complex compound has to be written.
Concept Introduction:
Systematic naming is the standard name given in a systematic way to a unique complex compound.
Systematic naming for the complex compound can be given based on the few important guidelines given below:
- 6. The name of the ligand is followed by the name of the central metal cation of a complex compound.
- 7. If there is more than one type of ligand, then their names are arranged in an alphabetical order.
- 8. More than one ligand of the same type have to be numbered using the Greek prefixes such as di, tri, tetra, penta, and hexa which represent the count of 1,2,3,4.5 and 6 respectively.
- 9. The roman numerals immediately following the metal ion name is the oxidation number of the metal
- 10. If the net charge of the complex ion is -ve, the central metal name should end with the suffix word –ate. Whereas if the net charge of the complex ion is +ve, then the central metal name should end with the suffix word –um.
(c)
Interpretation:
The formula for the given name of the complex compound has to be written.
Concept Introduction:
Systematic naming is the standard name given in a systematic way to a unique complex compound.
Systematic naming for the complex compound can be given based on the few important guidelines given below:
- 11. The name of the ligand is followed by the name of the central metal cation of a complex compound.
- 12. If there is more than one type of ligand, then their names are arranged in an alphabetical order.
- 13. More than one ligand of the same type have to be numbered using the Greek prefixes such as di, tri, tetra, penta, and hexa which represent the count of 1,2,3,4.5 and 6 respectively.
- 14. The roman numerals immediately following the metal ion name is the oxidation number of the metal
- 15. If the net charge of the complex ion is -ve, the central metal name should end with the suffix word –ate. Whereas if the net charge of the complex ion is +ve, then the central metal name should end with the suffix word –um.
(d)
Interpretation:
The formula for the given name of the complex compound has to be written.
Concept Introduction:
Systematic naming is the standard name given in a systematic way to a unique complex compound.
Systematic naming for the complex compound can be given based on the few important guidelines given below:
- 16. The name of the ligand is followed by the name of the central metal cation of a complex compound.
- 17. If there is more than one type of ligand, then their names are arranged in an alphabetical order.
- 18. More than one ligand of the same type have to be numbered using the Greek prefixes such as di, tri, tetra, penta, and hexa which represent the count of 1,2,3,4.5 and 6 respectively.
- 19. The roman numerals immediately following the metal ion name is the oxidation number of the metal
- 20. If the net charge of the complex ion is -ve, the central metal name should end with the suffix word –ate. Whereas if the net charge of the complex ion is +ve, then the central metal name should end with the suffix word –um.
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Chapter 23 Solutions
EBK CHEMISTRY
- Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. OH HO CI Br H CI CI Br CI CI Xf x f g Br D OH Br Br H₂N R. IN Ill I -N S OMe D II H CO₂H 1/111 DuckDuckGarrow_forwardThese are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material! ? H Harrow_forwardQ5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship between each pair of the stereoisomers you have drawn.arrow_forward
- Classify each pair of molecules according to whether or not they can participate in hydrogen bonding with one another. Participate in hydrogen bonding CH3COCH3 and CH3COCH2CH3 H2O and (CH3CH2)2CO CH3COCH3 and CH₂ CHO Answer Bank Do not participate in hydrogen bonding CH3CH2OH and HCHO CH3COCH2CH3 and CH3OHarrow_forwardNonearrow_forwardQ4: Comparing (3S,4S)-3,4-dimethylhexane and (3R,4S)-3,4-dimethylhexane, which one is optically active? Briefly explain.arrow_forward
- Nonearrow_forwardNonearrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 4A (g) + 2B (g) → 2C (g) + 7D (g) AHrxn =?kJ Substance AH in kJ/mol A (g) - 20.42 B (g) + 32.18 C (g) - 72.51 D (g) - 17.87arrow_forward
- Determine ASran for Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(aq) given the following information: Standard Entropy Values of Various Substance Substance So (J/mol • K) 60.9 Zn(s) HCl(aq) 56.5 130.58 H2(g) Zn2+(aq) -106.5 55.10 CI (aq)arrow_forward3) Catalytic hydrogenation of the compound below produced the expected product. However, a byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?arrow_forwardWhat is the ΔHorxn of the reaction? NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq) ΔHorxn 1= ________ kJ/molarrow_forward
- Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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